Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut; C. Avci-Camur; J. Troyano; A. Legrand; J. Canivet; I. Imaz; D. Maspoch; H. Reinsch; D. Farrusseng

doi:10.1039/c7ce00338b

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch, D. Farrusseng

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

74 Citas (Scopus)

Resumen

© 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

Idioma original	Inglés
Páginas (desde-hasta)	4211-4218
Publicación	CrystEngComm
Volumen	19
N.º	29
DOI	https://doi.org/10.1039/c7ce00338b
Estado	Publicada - 1 ene 2017

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abstract = "{\textcopyright} 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.",

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AU - Dhainaut, J.

AU - Avci-Camur, C.

AU - Troyano, J.

AU - Legrand, A.

AU - Canivet, J.

AU - Imaz, I.

AU - Maspoch, D.

AU - Reinsch, H.

AU - Farrusseng, D.

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N2 - © 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

AB - © 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

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JF - CrystEngComm

IS - 29

ER -

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

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