TY - JOUR
T1 - Synthesis, Structure, and Reactivity of a Stable Phosphonium–Sulfinyl Yldiide
AU - Garduno-Alva, Azucena
AU - Lenk, Romaric
AU - Escudié, Yannick
AU - González, Mariana Lozano
AU - Bousquet, Laura
AU - Saffon-Merceron, Nathalie
AU - Toledano, Cecilio Alvarez
AU - Bagan, Xavier
AU - Branchadell, Vicenç
AU - Maerten, Eddy
AU - Baceiredo, Antoine
PY - 2017/1/1
Y1 - 2017/1/1
N2 - © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis of a stable lithium phosphonium–sulfinyl yldiide was explored. The compound was fully characterized by NMR spectroscopy and X-ray crystallography. The electronic structure of 2 was analyzed by DFT calculations, which indicated strong ylidic character. Yldiide 2 was stable enough to catalyze the hydroacylation of benzaldehyde. More interestingly, the Wittig reaction with activated ketones proceeded smoothly at room temperature owing to the presence of the lithium cation.
AB - © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim The synthesis of a stable lithium phosphonium–sulfinyl yldiide was explored. The compound was fully characterized by NMR spectroscopy and X-ray crystallography. The electronic structure of 2 was analyzed by DFT calculations, which indicated strong ylidic character. Yldiide 2 was stable enough to catalyze the hydroacylation of benzaldehyde. More interestingly, the Wittig reaction with activated ketones proceeded smoothly at room temperature owing to the presence of the lithium cation.
KW - Phosphorus
KW - Structure elucidation
KW - Wittig reactions
KW - Yldiides
KW - Ylides
UR - https://www.scopus.com/pages/publications/85026365086
U2 - 10.1002/ejic.201700648
DO - 10.1002/ejic.201700648
M3 - Article
SN - 1434-1948
VL - 2017
SP - 3494
EP - 3497
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 29
ER -