Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption

Hao Li; Mathilde Ménard; Ani Vardanyan; Clarence Charnay; Laurence Raehm; Erwan Oliviero; Gulaim A. Seisenbaeva; Roser Pleixats; Jean Olivier Durand

doi:10.1039/d1ra01581h

Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption

Hao Li, Mathilde Ménard, Ani Vardanyan, Clarence Charnay, Laurence Raehm, Erwan Oliviero, Gulaim A. Seisenbaeva^*, Roser Pleixats, Jean Olivier Durand

^*Autor correspondiente de este trabajo

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6 Citas (Scopus)

Resumen

The synthesis through click chemistry of triethoxysilylated cyclen derivative-based ligands is described. Different methods were used such as the copper catalyzed Huisgen's reaction, or thiol-ene reaction for the functionalization of the cyclen scaffold with azidopropyltriethoxysilane or mercaptopropyltriethoxysilane, respectively. These ligands were then grafted on magnetic mesoporous silica nanoparticles (MMSN) for extraction and separation of Ni(ii) and Co(ii) metal ions from model solutions. The bare and ligand-modified MMSN materials revealed high adsorption capacity (1.0-2.13 mmol g⁻¹) and quick adsorption kinetics, achieving over 80% of the total capacity in 1-2 hours.

Idioma original	Inglés
Páginas (desde-hasta)	10777-10784
Número de páginas	8
Publicación	RSC ADVANCES
Volumen	11
N.º	18
DOI	https://doi.org/10.1039/d1ra01581h
Estado	Publicada - 12 mar 2021

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QUIMICA ORGANOFLUORADA: METODOS EMERGENTES DE FLUORACION Y TEJIDOS DE ALGODON PARA USOS MEDICOS
Vallribera Masso, A. (Investigador/a principal), Pleixats Rovira, R. (Co-Investigador/a Principal), Fernandez Freixes, G. (Colaborador/a), Granados Toda, A. (Colaborador/a), Li , H. (Colaborador/a), Liu, M. (Colaborador/a), Gimbert Suriñach, C. (Colaborador/a) & Gallego Gamo, A. (Colaborador/a)
Ministerio de Economía y Competitividad (MINECO), Fondo Europeo de Desarrollo Regional (FEDER)
1/01/19 → 30/09/22
Proyecto: Proyectos y Ayudas de Investigación

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@article{0757953e1c2d434e99a225e7a39ff9e1,

title = "Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption",

abstract = "The synthesis through click chemistry of triethoxysilylated cyclen derivative-based ligands is described. Different methods were used such as the copper catalyzed Huisgen's reaction, or thiol-ene reaction for the functionalization of the cyclen scaffold with azidopropyltriethoxysilane or mercaptopropyltriethoxysilane, respectively. These ligands were then grafted on magnetic mesoporous silica nanoparticles (MMSN) for extraction and separation of Ni(ii) and Co(ii) metal ions from model solutions. The bare and ligand-modified MMSN materials revealed high adsorption capacity (1.0-2.13 mmol g−1) and quick adsorption kinetics, achieving over 80\% of the total capacity in 1-2 hours.",

author = "Hao Li and Mathilde M{\'e}nard and Ani Vardanyan and Clarence Charnay and Laurence Raehm and Erwan Oliviero and Seisenbaeva, \{Gulaim A.\} and Roser Pleixats and Durand, \{Jean Olivier\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = mar,

day = "12",

doi = "10.1039/d1ra01581h",

language = "English",

volume = "11",

pages = "10777--10784",

journal = "RSC ADVANCES",

issn = "2046-2069",

number = "18",

}

Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption. / Li, Hao; Ménard, Mathilde; Vardanyan, Ani et al.
En: RSC ADVANCES, Vol. 11, N.º 18, 12.03.2021, p. 10777-10784.

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

TY - JOUR

T1 - Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption

AU - Li, Hao

AU - Ménard, Mathilde

AU - Vardanyan, Ani

AU - Charnay, Clarence

AU - Raehm, Laurence

AU - Oliviero, Erwan

AU - Seisenbaeva, Gulaim A.

AU - Pleixats, Roser

AU - Durand, Jean Olivier

PY - 2021/3/12

Y1 - 2021/3/12

N2 - The synthesis through click chemistry of triethoxysilylated cyclen derivative-based ligands is described. Different methods were used such as the copper catalyzed Huisgen's reaction, or thiol-ene reaction for the functionalization of the cyclen scaffold with azidopropyltriethoxysilane or mercaptopropyltriethoxysilane, respectively. These ligands were then grafted on magnetic mesoporous silica nanoparticles (MMSN) for extraction and separation of Ni(ii) and Co(ii) metal ions from model solutions. The bare and ligand-modified MMSN materials revealed high adsorption capacity (1.0-2.13 mmol g−1) and quick adsorption kinetics, achieving over 80% of the total capacity in 1-2 hours.

AB - The synthesis through click chemistry of triethoxysilylated cyclen derivative-based ligands is described. Different methods were used such as the copper catalyzed Huisgen's reaction, or thiol-ene reaction for the functionalization of the cyclen scaffold with azidopropyltriethoxysilane or mercaptopropyltriethoxysilane, respectively. These ligands were then grafted on magnetic mesoporous silica nanoparticles (MMSN) for extraction and separation of Ni(ii) and Co(ii) metal ions from model solutions. The bare and ligand-modified MMSN materials revealed high adsorption capacity (1.0-2.13 mmol g−1) and quick adsorption kinetics, achieving over 80% of the total capacity in 1-2 hours.

UR - https://www.scopus.com/pages/publications/85102799419

U2 - 10.1039/d1ra01581h

DO - 10.1039/d1ra01581h

M3 - Article

AN - SCOPUS:85102799419

SN - 2046-2069

VL - 11

SP - 10777

EP - 10784

JO - RSC ADVANCES

JF - RSC ADVANCES

IS - 18

ER -

Synthesis of triethoxysilylated cyclen derivatives, grafting on magnetic mesoporous silica nanoparticles and application to metal ion adsorption

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QUIMICA ORGANOFLUORADA: METODOS EMERGENTES DE FLUORACION Y TEJIDOS DE ALGODON PARA USOS MEDICOS

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