Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

Nicola Dellus; Tsuyoshi Kato; Nathalie Saffon-Merceron; Vicenç Branchadell; Antoine Baceiredo

doi:10.1021/ic2013182

Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

Nicola Dellus, Tsuyoshi Kato, Nathalie Saffon-Merceron, Vicenç Branchadell, Antoine Baceiredo

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

16 Citas (Scopus)

Resumen

The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

Idioma original	Inglés
Páginas (desde-hasta)	7949-7951
Publicación	Inorganic Chemistry
Volumen	50
N.º	17
DOI	https://doi.org/10.1021/ic2013182
Estado	Publicada - 5 sept 2011

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abstract = "The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. {\textcopyright} 2011 American Chemical Society.",

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T1 - Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

AU - Dellus, Nicola

AU - Kato, Tsuyoshi

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Baceiredo, Antoine

PY - 2011/9/5

Y1 - 2011/9/5

N2 - The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

AB - The mixed P,S-bisylide 1 reacts with phosphenium salts, affording phosphoniophosphinocarbenes, with elimination of diphenyl sulfide. Using a more compact cyclic phosphenium cation, the reaction leads to the formation of an original three-membered heterocycle featuring a gem-bisylide function. This molecule represents the first isolable analogue of the phosphirenyl anion derivative. © 2011 American Chemical Society.

UR - https://www.scopus.com/pages/publications/80052252495

U2 - 10.1021/ic2013182

DO - 10.1021/ic2013182

M3 - Article

SN - 0020-1669

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JO - Inorganic Chemistry

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Synthesis and characterization of a stable cyclic gem-bis(phosphaylide): A 4π-electron three-membered heterocycle

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