TY - JOUR
T1 - Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra
AU - Von Baeckmann, Cornelia
AU - Ruiz Relaño, Sara
AU - Imaz, Inhar
AU - Handke, Marcel
AU - Juanhuix, Judith
AU - Gándara, Felipe
AU - Carné-Sánchez, Arnau
AU - Maspoch Comamala, Daniel
PY - 2023
Y1 - 2023
N2 - Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic. We present a novel strategy to assemble diverse metal ions and organic linkers into metal-organic polyhedra (MOPs). It involves use of a pre-assembled complex of a parent MOP to replicate this cage with a multicomponent character.
AB - Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic. We present a novel strategy to assemble diverse metal ions and organic linkers into metal-organic polyhedra (MOPs). It involves use of a pre-assembled complex of a parent MOP to replicate this cage with a multicomponent character.
U2 - 10.1039/d2cc06815j
DO - 10.1039/d2cc06815j
M3 - Article
C2 - 36853262
SN - 1359-7345
VL - 59
SP - 3423
EP - 3426
JO - Chemical Communications
JF - Chemical Communications
IS - 23
ER -