Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa; J. C. Bayón

doi:10.1039/b105208j

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa, J. C. Bayón

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

21 Citas (Scopus)

Resumen

A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

Idioma original	Inglés
Páginas (desde-hasta)	2067-2068
Publicación	Journal of the Chemical Society, Dalton Transactions
N.º	14
DOI	https://doi.org/10.1039/b105208j
Estado	Publicada - 9 ago 2001

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title = "Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring",

abstract = "A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70\% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.",

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AU - Freixa, Z.

AU - Bayón, J. C.

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Y1 - 2001/8/9

N2 - A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

AB - A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

UR - https://www.scopus.com/pages/publications/0034742921

U2 - 10.1039/b105208j

DO - 10.1039/b105208j

M3 - Article

SN - 1470-479X

SP - 2067

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 14

ER -

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

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