Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Maria de Moragas; Adriana Port; Xavier Sánchez-Ruiz; Carlos Jaime; Christian Roussel; Albert Virgili

doi:10.1016/0957-4166(95)00164-K

Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Maria de Moragas, Adriana Port, Xavier Sánchez-Ruiz, Carlos Jaime, Christian Roussel, Albert Virgili

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

9 Citas (Scopus)

Resumen

The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

Idioma original	Inglés
Páginas (desde-hasta)	1307-1310
Publicación	Tetrahedron: asymmetry
Volumen	6
N.º	6
DOI	https://doi.org/10.1016/0957-4166(95)00164-K
Estado	Publicada - 1 ene 1995

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abstract = "The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. {\textcopyright} 1995.",

author = "\{de Moragas\}, Maria and Adriana Port and Xavier S{\'a}nchez-Ruiz and Carlos Jaime and Christian Roussel and Albert Virgili",

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Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives. / de Moragas, Maria; Port, Adriana; Sánchez-Ruiz, Xavier et al.
En: Tetrahedron: asymmetry, Vol. 6, N.º 6, 01.01.1995, p. 1307-1310.

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

TY - JOUR

T1 - Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

AU - de Moragas, Maria

AU - Port, Adriana

AU - Sánchez-Ruiz, Xavier

AU - Jaime, Carlos

AU - Roussel, Christian

AU - Virgili, Albert

PY - 1995/1/1

Y1 - 1995/1/1

N2 - The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

AB - The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.

UR - https://www.scopus.com/pages/publications/0029013941

U2 - 10.1016/0957-4166(95)00164-K

DO - 10.1016/0957-4166(95)00164-K

M3 - Article

SN - 0957-4166

VL - 6

SP - 1307

EP - 1310

JO - Tetrahedron: asymmetry

JF - Tetrahedron: asymmetry

IS - 6

ER -

Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

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