Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas; Agustí Lledós; Montserrat Oliván; Enrique Oñate; María A. Tajada; Gregori Ujaque

doi:10.1021/om030229y

Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas, Agustí Lledós, Montserrat Oliván, Enrique Oñate, María A. Tajada, Gregori Ujaque

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

61 Citas (Scopus)

Resumen

Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

Idioma original	Inglés
Páginas (desde-hasta)	3753-3765
Publicación	Organometallics
Volumen	22
N.º	18
DOI	https://doi.org/10.1021/om030229y
Estado	Publicada - 1 sept 2003

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title = "Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex",

abstract = "Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.",

author = "Esteruelas, {Miguel A.} and Agust{\'i} Lled{\'o}s and Montserrat Oliv{\'a}n and Enrique O{\~n}ate and Tajada, {Mar{\'i}a A.} and Gregori Ujaque",

year = "2003",

month = sep,

day = "1",

doi = "10.1021/om030229y",

language = "English",

volume = "22",

pages = "3753--3765",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "18",

}

Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex. / Esteruelas, Miguel A.; Lledós, Agustí; Oliván, Montserrat et al.
En: Organometallics, Vol. 22, N.º 18, 01.09.2003, p. 3753-3765.

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

TY - JOUR

T1 - Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

AU - Esteruelas, Miguel A.

AU - Lledós, Agustí

AU - Oliván, Montserrat

AU - Oñate, Enrique

AU - Tajada, María A.

AU - Ujaque, Gregori

PY - 2003/9/1

Y1 - 2003/9/1

N2 - Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

AB - Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.

U2 - 10.1021/om030229y

DO - 10.1021/om030229y

M3 - Article

SN - 0276-7333

VL - 22

SP - 3753

EP - 3765

JO - Organometallics

JF - Organometallics

IS - 18

ER -

Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

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