Michael additions catalyzed by phosphines. An overlooked synthetic method

Carolina Gimbert; Maria Lumbierres; Caroline Marchi; Marcial Moreno-Mañas; Rosa M. Sebastián; Adelina Vallribera

doi:10.1016/j.tet.2005.07.005

Michael additions catalyzed by phosphines. An overlooked synthetic method

Carolina Gimbert, Maria Lumbierres, Caroline Marchi, Marcial Moreno-Mañas, Rosa M. Sebastián, Adelina Vallribera

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

96 Citas (Scopus)

Resumen

Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

Idioma original	Inglés
Páginas (desde-hasta)	8598-8605
Publicación	Tetrahedron
Volumen	61
N.º	36
DOI	https://doi.org/10.1016/j.tet.2005.07.005
Estado	Publicada - 5 sept 2005

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title = "Michael additions catalyzed by phosphines. An overlooked synthetic method",

abstract = "Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. {\textcopyright} 2005 Elsevier Ltd. All rights reserved.",

keywords = "β-Dicarbonyl compounds, Conjugate addition, Organocatalysis, Phosphines",

author = "Carolina Gimbert and Maria Lumbierres and Caroline Marchi and Marcial Moreno-Ma{\~n}as and Sebasti{\'a}n, \{Rosa M.\} and Adelina Vallribera",

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AU - Gimbert, Carolina

AU - Lumbierres, Maria

AU - Marchi, Caroline

AU - Moreno-Mañas, Marcial

AU - Sebastián, Rosa M.

AU - Vallribera, Adelina

PY - 2005/9/5

Y1 - 2005/9/5

N2 - Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

AB - Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method. © 2005 Elsevier Ltd. All rights reserved.

KW - β-Dicarbonyl compounds

KW - Conjugate addition

KW - Organocatalysis

KW - Phosphines

UR - https://www.scopus.com/pages/publications/23444440146

U2 - 10.1016/j.tet.2005.07.005

DO - 10.1016/j.tet.2005.07.005

M3 - Article

SN - 0040-4020

VL - 61

SP - 8598

EP - 8605

JO - Tetrahedron

JF - Tetrahedron

IS - 36

ER -

Michael additions catalyzed by phosphines. An overlooked synthetic method

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