Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas; A. Trius

doi:10.1016/S0040-4020(01)98915-X

Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas, A. Trius

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

25 Citas (Scopus)

Resumen

Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

Idioma original	Inglés
Páginas (desde-hasta)	3009-3015
Publicación	Tetrahedron
Volumen	37
N.º	17
DOI	https://doi.org/10.1016/S0040-4020(01)98915-X
Estado	Publicada - 1 ene 1981

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abstract = "Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. {\textcopyright} 1981.",

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N2 - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

AB - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

UR - https://www.scopus.com/pages/publications/0001375618

U2 - 10.1016/S0040-4020(01)98915-X

DO - 10.1016/S0040-4020(01)98915-X

M3 - Article

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JO - Tetrahedron

JF - Tetrahedron

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