Gold-catalyzed cycloadditions involving allenes: Mechanistic insights from theoretical studies

Sergi Montserrat; Gregori Ujaque; Fernando López; José L. Mascareñas; Agustí Lledós

doi:10.1007/128_2010_121

Gold-catalyzed cycloadditions involving allenes: Mechanistic insights from theoretical studies

Sergi Montserrat, Gregori Ujaque, Fernando López, José L. Mascareñas, Agustí Lledós

Departamento de Química

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

32 Citas (Scopus)

Resumen

Allenes, owing to their special structural characteristics related to the presence of two π bonds in a formally strained manner, are particularly prone to undergo gold-activated reactions, particularly cycloaddition processes. Theoretical studies based on DFT calculations have been very useful to explain observed reactivities and advance mechanistic proposals. © 2011 Springer-Verlag Berlin Heidelberg.

Idioma original	Inglés
Páginas (desde-hasta)	225-248
Publicación	Topics in Current Chemistry
Volumen	302
DOI	https://doi.org/10.1007/128_2010_121
Estado	Publicada - 1 ago 2011

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abstract = "Allenes, owing to their special structural characteristics related to the presence of two π bonds in a formally strained manner, are particularly prone to undergo gold-activated reactions, particularly cycloaddition processes. Theoretical studies based on DFT calculations have been very useful to explain observed reactivities and advance mechanistic proposals. {\textcopyright} 2011 Springer-Verlag Berlin Heidelberg.",

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AU - Ujaque, Gregori

AU - López, Fernando

AU - Mascareñas, José L.

AU - Lledós, Agustí

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N2 - Allenes, owing to their special structural characteristics related to the presence of two π bonds in a formally strained manner, are particularly prone to undergo gold-activated reactions, particularly cycloaddition processes. Theoretical studies based on DFT calculations have been very useful to explain observed reactivities and advance mechanistic proposals. © 2011 Springer-Verlag Berlin Heidelberg.

AB - Allenes, owing to their special structural characteristics related to the presence of two π bonds in a formally strained manner, are particularly prone to undergo gold-activated reactions, particularly cycloaddition processes. Theoretical studies based on DFT calculations have been very useful to explain observed reactivities and advance mechanistic proposals. © 2011 Springer-Verlag Berlin Heidelberg.

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KW - Cycloaddition

KW - DFT studies

KW - Gold catalysis

KW - Reaction mechanisms

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Gold-catalyzed cycloadditions involving allenes: Mechanistic insights from theoretical studies

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