Electrochemical synthesis of nitroaromatic ketones

Producción científica: Contribución a una revistaArtículoInvestigaciónrevisión exhaustiva

25 Citas (Scopus)

Resumen

Nitroaromatic ketones are readily prepared by nucleophilic aromatic substitution of hydrogen in nitroarenes by electrochemical oxidation. Carbanions of various ketones were added to selected nitroarenes in DMF/ketone mixtures leading to formation of the o11 complexes. The reaction was promoted using potassium feri-butoxide as a base. Useful yields were achieved (80-100%) in the C-arylation of ketones. In most cases, the process proceeded with high selectivity. This new method represents an environmentally favourable route for obtaining nitroaromatic ketones. © WILEY-VCH Verlag GmbH, 2002.
Idioma originalInglés
Páginas (desde-hasta)261-267
PublicaciónEuropean Journal of Organic Chemistry
Volumen2
N.º2
DOI
EstadoPublicada - 1 ene 2002

Huella

Profundice en los temas de investigación de 'Electrochemical synthesis of nitroaromatic ketones'. En conjunto forman una huella única.

Citar esto