TY - JOUR
T1 - Direct on-surface patterning of a crystalline laminar covalent organic framework synthesized at room temperature
AU - De la Peña, Alejandro
AU - Rodríguez-San-Miguel, David
AU - Stylianou, Kyriakos C.
AU - Cavallini, Massimiliano
AU - Gentili, Denis
AU - Liscio, Fabiola
AU - Milita, Silvia
AU - Roscioni, Otello Maria
AU - Ruiz-González, Maria Luisa
AU - Carbonell Fernández, Carlos
AU - Maspoch Comamala, Daniel
AU - Mas Balleste, Ruben
AU - Segura, José Luis
AU - Zamora, Félix
PY - 2015
Y1 - 2015
N2 - We report herein an efficient, fast, and simple synthesis of an imine-based covalent organic framework (COF) at room temperature (hereafter, RT-COF-1). RT-COF-1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N and CO. The room-temperature synthesis has enabled us to fabricate and position low-cost micro- and submicropatterns of RT-COF-1 on several surfaces, including solid SiO substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink-jet printing.
AB - We report herein an efficient, fast, and simple synthesis of an imine-based covalent organic framework (COF) at room temperature (hereafter, RT-COF-1). RT-COF-1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N and CO. The room-temperature synthesis has enabled us to fabricate and position low-cost micro- and submicropatterns of RT-COF-1 on several surfaces, including solid SiO substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink-jet printing.
KW - Covalent
KW - Organic
KW - Frameworks
KW - Ink-jet printing
KW - Porous crystalline materials
KW - Processability
KW - Soft-lithography
UR - https://www.scopus.com/pages/publications/84936994579
U2 - 10.1002/chem.201501692
DO - 10.1002/chem.201501692
M3 - Article
SN - 1521-3765
VL - 21
SP - 10666
EP - 10670
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 30
ER -