Design of zn-, cu-, and fe-coordination complexes confined in a self-Assembled nanocage

Cédric Colomban; Vlad Martin-Diaconescu; Teodor Parella; Sébastien Goeb; Cristina García-Simón; Julio Lloret-Fillol; Miquel Costas; Xavi Ribas

doi:10.1021/acs.inorgchem.7b02852

Design of zn-, cu-, and fe-coordination complexes confined in a self-Assembled nanocage

Cédric Colomban, Vlad Martin-Diaconescu, Teodor Parella, Sébastien Goeb, Cristina García-Simón, Julio Lloret-Fillol, Miquel Costas, Xavi Ribas

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© 2018 American Chemical Society. The encapsulation of coordination complexes in a tetragonal prismatic nanocage (1·(BArF)8) built from Zn-porphyrin and macrocyclic Pd-clip-based synthons is described. The functional duality of the guest ligand L1 allows for its encapsulation inside the cage 1·(BArF)8, along with the simultaneous coordination of ZnII, CuII, or FeIII metal ions. Remarkably, the coordination chemistry inside the host-guest adduct L1âŠ'1·(BArF)8 occurs in both solution solution and solid state. The resulting confined metallocomplexes have been characterized by means of UV-vis, ESI-HRMS, NMR, and EPR techniques. Furthermore, the emission of the Zn-porphyrin fluorophores of 1·(BArF)8 is strongly quenched by the encapsulation of paramagnetic complexes, representing a remarkable example of guest-dependent tuning of the host fluorescence.

Idioma original	Inglés
Páginas (desde-hasta)	3529-3539
Publicación	Inorganic Chemistry
Volumen	57
N.º	7
DOI	https://doi.org/10.1021/acs.inorgchem.7b02852
Estado	Publicada - 2 abr 2018

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title = "Design of zn-, cu-, and fe-coordination complexes confined in a self-Assembled nanocage",

abstract = "{\textcopyright} 2018 American Chemical Society. The encapsulation of coordination complexes in a tetragonal prismatic nanocage (1·(BArF)8) built from Zn-porphyrin and macrocyclic Pd-clip-based synthons is described. The functional duality of the guest ligand L1 allows for its encapsulation inside the cage 1·(BArF)8, along with the simultaneous coordination of ZnII, CuII, or FeIII metal ions. Remarkably, the coordination chemistry inside the host-guest adduct L1{\^a}{\v S}'1·(BArF)8 occurs in both solution solution and solid state. The resulting confined metallocomplexes have been characterized by means of UV-vis, ESI-HRMS, NMR, and EPR techniques. Furthermore, the emission of the Zn-porphyrin fluorophores of 1·(BArF)8 is strongly quenched by the encapsulation of paramagnetic complexes, representing a remarkable example of guest-dependent tuning of the host fluorescence.",

author = "C{\'e}dric Colomban and Vlad Martin-Diaconescu and Teodor Parella and S{\'e}bastien Goeb and Cristina Garc{\'i}a-Sim{\'o}n and Julio Lloret-Fillol and Miquel Costas and Xavi Ribas",

year = "2018",

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doi = "10.1021/acs.inorgchem.7b02852",

language = "English",

volume = "57",

pages = "3529--3539",

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TY - JOUR

T1 - Design of zn-, cu-, and fe-coordination complexes confined in a self-Assembled nanocage

AU - Colomban, Cédric

AU - Martin-Diaconescu, Vlad

AU - Parella, Teodor

AU - Goeb, Sébastien

AU - García-Simón, Cristina

AU - Lloret-Fillol, Julio

AU - Costas, Miquel

AU - Ribas, Xavi

PY - 2018/4/2

Y1 - 2018/4/2

N2 - © 2018 American Chemical Society. The encapsulation of coordination complexes in a tetragonal prismatic nanocage (1·(BArF)8) built from Zn-porphyrin and macrocyclic Pd-clip-based synthons is described. The functional duality of the guest ligand L1 allows for its encapsulation inside the cage 1·(BArF)8, along with the simultaneous coordination of ZnII, CuII, or FeIII metal ions. Remarkably, the coordination chemistry inside the host-guest adduct L1âŠ'1·(BArF)8 occurs in both solution solution and solid state. The resulting confined metallocomplexes have been characterized by means of UV-vis, ESI-HRMS, NMR, and EPR techniques. Furthermore, the emission of the Zn-porphyrin fluorophores of 1·(BArF)8 is strongly quenched by the encapsulation of paramagnetic complexes, representing a remarkable example of guest-dependent tuning of the host fluorescence.

AB - © 2018 American Chemical Society. The encapsulation of coordination complexes in a tetragonal prismatic nanocage (1·(BArF)8) built from Zn-porphyrin and macrocyclic Pd-clip-based synthons is described. The functional duality of the guest ligand L1 allows for its encapsulation inside the cage 1·(BArF)8, along with the simultaneous coordination of ZnII, CuII, or FeIII metal ions. Remarkably, the coordination chemistry inside the host-guest adduct L1âŠ'1·(BArF)8 occurs in both solution solution and solid state. The resulting confined metallocomplexes have been characterized by means of UV-vis, ESI-HRMS, NMR, and EPR techniques. Furthermore, the emission of the Zn-porphyrin fluorophores of 1·(BArF)8 is strongly quenched by the encapsulation of paramagnetic complexes, representing a remarkable example of guest-dependent tuning of the host fluorescence.

U2 - 10.1021/acs.inorgchem.7b02852

DO - 10.1021/acs.inorgchem.7b02852

M3 - Review article

C2 - 29293325

SN - 0020-1669

VL - 57

SP - 3529

EP - 3539

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Design of zn-, cu-, and fe-coordination complexes confined in a self-Assembled nanocage

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