TY - JOUR
T1 - Characterization and performance of electrostatically adsorbed Ru-Hbpp water oxidation catalysts
AU - Aguiló, Joan
AU - Francàs, Laia
AU - Liu, Hai Jie
AU - Bofill, Roger
AU - García-Antón, Jordi
AU - Benet-Buchholz, Jordi
AU - Llobet, Antoni
AU - Escriche, Lluís
AU - Sala, Xavier
PY - 2014/1/1
Y1 - 2014/1/1
N2 - A new family of Ru-Hbpp dinuclear complexes containing the positively charged terpyridine derivative ligand 4-(-p-(pyridin-1-ylmethyl)phenyl)-2, 2′:6′,2′-terpyridine of general formula {[Ru(L1 +)]2(μ-bpp)(L-L)}m+ (L-L = μ-Cl, μ-acetato, or (H2O)2; m = 4 or 5) have been synthesized and fully characterized, both in the solid state (X-ray diffraction) and in solution (1D and 2D NMR spectroscopy, UV-vis spectroscopy and electrochemical techniques). New hybrid materials have been prepared by the electrostatic interaction of these complexes with several oxidatively rugged solid supports such as SiO2, FTO-TiO2 and FTO-Nafion®. These new hybrid materials were prepared and catalytically evaluated with regard to their capacity to chemically and electrochemically oxidize water to dioxygen. © 2014 The Royal Society of Chemistry.
AB - A new family of Ru-Hbpp dinuclear complexes containing the positively charged terpyridine derivative ligand 4-(-p-(pyridin-1-ylmethyl)phenyl)-2, 2′:6′,2′-terpyridine of general formula {[Ru(L1 +)]2(μ-bpp)(L-L)}m+ (L-L = μ-Cl, μ-acetato, or (H2O)2; m = 4 or 5) have been synthesized and fully characterized, both in the solid state (X-ray diffraction) and in solution (1D and 2D NMR spectroscopy, UV-vis spectroscopy and electrochemical techniques). New hybrid materials have been prepared by the electrostatic interaction of these complexes with several oxidatively rugged solid supports such as SiO2, FTO-TiO2 and FTO-Nafion®. These new hybrid materials were prepared and catalytically evaluated with regard to their capacity to chemically and electrochemically oxidize water to dioxygen. © 2014 The Royal Society of Chemistry.
U2 - 10.1039/c3cy00643c
DO - 10.1039/c3cy00643c
M3 - Article
SN - 2044-4753
VL - 4
SP - 190
EP - 199
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
IS - 1
ER -