Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ2N 1:N2] bis[(η41, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

Glòria Esquius; Josefina Pons; Ramón Yáñez; Josep Ros; Xavier Solans; Mercè Font-Bardia

doi:10.1107/S0108270101020017

Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ²N ¹:N²] bis[(η⁴1, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

Glòria Esquius, Josefina Pons, Ramón Yáñez, Josep Ros, Xavier Solans, Mercè Font-Bardia

Departamento de Química

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15 Citas (Scopus)

Resumen

The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.

Idioma original	Inglés
Páginas (desde-hasta)	m133-m134
Publicación	Acta Crystallographica Section C: Crystal Structure Communications
Volumen	58
N.º	2
DOI	https://doi.org/10.1107/S0108270101020017
Estado	Publicada - 1 ene 2002

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@article{b17d201e81944fd5bd57a7a32c02fbac,

title = "Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ2N 1:N2] bis[(η41, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate",

abstract = "The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.",

author = "Gl{\`o}ria Esquius and Josefina Pons and Ram{\'o}n Y{\'a}{\~n}ez and Josep Ros and Xavier Solans and Merc{\`e} Font-Bardia",

year = "2002",

month = jan,

day = "1",

doi = "10.1107/S0108270101020017",

language = "English",

volume = "58",

pages = "m133--m134",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

}

Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ²N ¹:N²] bis[(η⁴1, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate. / Esquius, Glòria; Pons, Josefina ; Yáñez, Ramón et al.
En: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, N.º 2, 01.01.2002, p. m133-m134.

Producción científica: Contribución a una revista › Artículo › Investigación › revisión exhaustiva

TY - JOUR

T1 - Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ2N 1:N2] bis[(η41, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

AU - Esquius, Glòria

AU - Pons, Josefina

AU - Yáñez, Ramón

AU - Ros, Josep

AU - Solans, Xavier

AU - Font-Bardia, Mercè

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.

AB - The molecular structure of the compound [Rh2(C8H15N3)2 (C8H12)2] Cl2·CH2Cl2·CH3OH was studied. The dinuclear Rh1 complex was found to have C2 symmetry with the two pyrazolato ligands acting as μ-bridges. The coordination of each Rh cation was completed by one cyclooctadiene (COD) ligand. The average Rh-C(COD) distance showed linear dependence on the Rh-N(pyrazole) distance due to steric hinderance produced by the packing.

U2 - 10.1107/S0108270101020017

DO - 10.1107/S0108270101020017

M3 - Article

SN - 0108-2701

VL - 58

SP - m133-m134

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ2N 1:N2] bis[(η41, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

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Bis[μ-4-(ethylammoniomethyl)-3, 5-dimethylpyrazolato-κ²N ¹:N²] bis[(η⁴1, 5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate