Zigzag Ligands for Transversal Design in Reticular Chemistry: Unveiling New Structural Opportunities for Metal-Organic Frameworks

Vincent Guillerm, Thais Grancha, Inhar Imaz, Judith Juanhuix, Daniel Maspoch

    Research output: Contribution to journalArticleResearchpeer-review

    37 Citations (Scopus)

    Abstract

    © 2018 American Chemical Society. Herein we describe the topological influence of zigzag ligands in the assembly of Zr(IV) metal-organic frameworks (MOFs). Through a transversal design strategy using reticular chemistry, we were able to synthesize a family of isoreticular Zr(IV)-based MOFs exhibiting the bcu - rather than the fcu - topology. Our findings underscore the value of the transversal parameter in organic ligands for dictating MOF architectures.
    Original languageEnglish
    Pages (from-to)10153-10157
    JournalJournal of the American Chemical Society
    Volume140
    Issue number32
    DOIs
    Publication statusPublished - 15 Aug 2018

    Fingerprint

    Dive into the research topics of 'Zigzag Ligands for Transversal Design in Reticular Chemistry: Unveiling New Structural Opportunities for Metal-Organic Frameworks'. Together they form a unique fingerprint.

    Cite this