Vibrational spectra and normal coordinate analysis of two isotopomers of the thiosulfate ion

Santiago Alvarez; Vlado Tabacik; Jaime Casabo

doi:10.1016/0022-2860(85)87005-8

Vibrational spectra and normal coordinate analysis of two isotopomers of the thiosulfate ion

Santiago Alvarez, Vlado Tabacik, Jaime Casabo

Department of Chemistry

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Abstract

The Raman spectra of 18O-thiosulfate ion (S1O-23) in H118O solution and the IR spectrum of 18O-sodium thiosulfate in the solid have been obtained. Normal Coordinate calculations fitting all the fundamental wavenumbers of both 16O and 18O isotopomers have been carried out transferring the GVFF of the sulfate ion as the starting point and employing a symmetry force field for the least-squares adjustment procedure. A comparison of the results is made with the known force fields for several sulfur compounds. © 1985.

Original language	English
Pages (from-to)	235-243
Journal	Journal of Molecular Structure
Volume	130
Issue number	3-4
DOIs	https://doi.org/10.1016/0022-2860(85)87005-8
Publication status	Published - 1 Jan 1985

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title = "Vibrational spectra and normal coordinate analysis of two isotopomers of the thiosulfate ion",

abstract = "The Raman spectra of 18O-thiosulfate ion (S1O-23) in H118O solution and the IR spectrum of 18O-sodium thiosulfate in the solid have been obtained. Normal Coordinate calculations fitting all the fundamental wavenumbers of both 16O and 18O isotopomers have been carried out transferring the GVFF of the sulfate ion as the starting point and employing a symmetry force field for the least-squares adjustment procedure. A comparison of the results is made with the known force fields for several sulfur compounds. {\textcopyright} 1985.",

author = "Santiago Alvarez and Vlado Tabacik and Jaime Casabo",

year = "1985",

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doi = "10.1016/0022-2860(85)87005-8",

language = "English",

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journal = "Journal of Molecular Structure",

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TY - JOUR

T1 - Vibrational spectra and normal coordinate analysis of two isotopomers of the thiosulfate ion

AU - Alvarez, Santiago

AU - Tabacik, Vlado

AU - Casabo, Jaime

PY - 1985/1/1

Y1 - 1985/1/1

N2 - The Raman spectra of 18O-thiosulfate ion (S1O-23) in H118O solution and the IR spectrum of 18O-sodium thiosulfate in the solid have been obtained. Normal Coordinate calculations fitting all the fundamental wavenumbers of both 16O and 18O isotopomers have been carried out transferring the GVFF of the sulfate ion as the starting point and employing a symmetry force field for the least-squares adjustment procedure. A comparison of the results is made with the known force fields for several sulfur compounds. © 1985.

AB - The Raman spectra of 18O-thiosulfate ion (S1O-23) in H118O solution and the IR spectrum of 18O-sodium thiosulfate in the solid have been obtained. Normal Coordinate calculations fitting all the fundamental wavenumbers of both 16O and 18O isotopomers have been carried out transferring the GVFF of the sulfate ion as the starting point and employing a symmetry force field for the least-squares adjustment procedure. A comparison of the results is made with the known force fields for several sulfur compounds. © 1985.

U2 - 10.1016/0022-2860(85)87005-8

DO - 10.1016/0022-2860(85)87005-8

M3 - Article

SN - 0022-2860

VL - 130

SP - 235

EP - 243

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 3-4

ER -

Vibrational spectra and normal coordinate analysis of two isotopomers of the thiosulfate ion

Abstract

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