Metal-organic nanoparticles (see SEM image) showing valence-tautomeric behavior have been obtained by a versatile approach involving precipitation and coordination polymerization. They undergo reversible temperature-dependent interconversion between low- and high-spin forms, as revealed by plotting the magnetic moment χ as a function of temperature. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
- Coordination polymers
- Magnetic properties