Valence-tautomeric metal-organic nanoparticles

Inhar Imaz, Daniel Maspoch, Clara Rodríguez-Blanco, José Manuel Pérez-Falcón, Javier Campo, Daniel Ruiz-Molina

    Research output: Contribution to journalArticleResearchpeer-review

    120 Citations (Scopus)

    Abstract

    Metal-organic nanoparticles (see SEM image) showing valence-tautomeric behavior have been obtained by a versatile approach involving precipitation and coordination polymerization. They undergo reversible temperature-dependent interconversion between low- and high-spin forms, as revealed by plotting the magnetic moment χ as a function of temperature. (Graph Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
    Original languageEnglish
    Pages (from-to)1857-1860
    JournalAngewandte Chemie - International Edition
    Volume47
    Issue number10
    DOIs
    Publication statusPublished - 22 Feb 2008

    Keywords

    • Cobalt
    • Coordination polymers
    • Magnetic properties
    • Nanostructures
    • Tautomerism

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