Utilisation of an η3-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η5-C <inf>5</inf>Me<inf>5</inf>)Rh(CH<inf>2</inf>=CHMe)

Catherine J. Sexton; Joaquín López-Serrano; Agustí Lledós; Simon B. Duckett

doi:10.1039/b809321k

Utilisation of an η3-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η5-C <inf>5</inf>Me<inf>5</inf>)Rh(CH<inf>2</inf>=CHMe)

Catherine J. Sexton, Joaquín López-Serrano, Agustí Lledós, Simon B. Duckett

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

Low temperature UV irradiation of solutions of (η5-C 5Me5)Rh(CH2=CHMe)2 yields (η5-C5Me5)Rh(η3-CH 2CHCH2)(H), which provides controlled access to the 16-electron fragment (η5-C5Me5)Rh(CH 2=CHMe). © The Royal Society of Chemistry.

Original language	English
Pages (from-to)	4834-4836
Journal	Chemical Communications
Issue number	39
DOIs	https://doi.org/10.1039/b809321k
Publication status	Published - 9 Oct 2008

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@article{efa7a02ce3004a59a68b9445266b8d73,

title = "Utilisation of an η3-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η5-C 5Me5)Rh(CH2=CHMe)",

abstract = "Low temperature UV irradiation of solutions of (η5-C 5Me5)Rh(CH2=CHMe)2 yields (η5-C5Me5)Rh(η3-CH 2CHCH2)(H), which provides controlled access to the 16-electron fragment (η5-C5Me5)Rh(CH 2=CHMe). {\textcopyright} The Royal Society of Chemistry.",

author = "Sexton, \{Catherine J.\} and Joaqu{\'i}n L{\'o}pez-Serrano and Agust{\'i} Lled{\'o}s and Duckett, \{Simon B.\}",

year = "2008",

month = oct,

day = "9",

doi = "10.1039/b809321k",

language = "English",

pages = "4834--4836",

number = "39",

}

Utilisation of an η3-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η5-C <inf>5</inf>Me<inf>5</inf>)Rh(CH<inf>2</inf>=CHMe). / Sexton, Catherine J.; López-Serrano, Joaquín; Lledós, Agustí et al.
In: Chemical Communications, No. 39, 09.10.2008, p. 4834-4836.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Utilisation of an η3-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η5-C 5Me5)Rh(CH2=CHMe)

AU - Sexton, Catherine J.

AU - López-Serrano, Joaquín

AU - Lledós, Agustí

AU - Duckett, Simon B.

PY - 2008/10/9

Y1 - 2008/10/9

N2 - Low temperature UV irradiation of solutions of (η5-C 5Me5)Rh(CH2=CHMe)2 yields (η5-C5Me5)Rh(η3-CH 2CHCH2)(H), which provides controlled access to the 16-electron fragment (η5-C5Me5)Rh(CH 2=CHMe). © The Royal Society of Chemistry.

AB - Low temperature UV irradiation of solutions of (η5-C 5Me5)Rh(CH2=CHMe)2 yields (η5-C5Me5)Rh(η3-CH 2CHCH2)(H), which provides controlled access to the 16-electron fragment (η5-C5Me5)Rh(CH 2=CHMe). © The Royal Society of Chemistry.

UR - https://www.scopus.com/pages/publications/54749092828

U2 - 10.1039/b809321k

DO - 10.1039/b809321k

M3 - Article

SN - 1359-7345

SP - 4834

EP - 4836

JO - Chemical Communications

JF - Chemical Communications

IS - 39

ER -

Utilisation of an η<sup>3</sup>-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η<sup>5</sup>-C <inf>5</inf>Me<inf>5</inf>)Rh(CH<inf>2</inf>=CHMe)

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