Utilisation of an η<sup>3</sup>-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (η<sup>5</sup>-C <inf>5</inf>Me<inf>5</inf>)Rh(CH<inf>2</inf>=CHMe)

Catherine J. Sexton, Joaquín López-Serrano, Agustí Lledós, Simon B. Duckett

Research output: Contribution to journalArticleResearchpeer-review

4 Citations (Scopus)

Abstract

Low temperature UV irradiation of solutions of (η5-C 5Me5)Rh(CH2=CHMe)2 yields (η5-C5Me5)Rh(η3-CH 2CHCH2)(H), which provides controlled access to the 16-electron fragment (η5-C5Me5)Rh(CH 2=CHMe). © The Royal Society of Chemistry.
Original languageEnglish
Pages (from-to)4834-4836
JournalChemical Communications
Issue number39
DOIs
Publication statusPublished - 9 Oct 2008

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