Use of 9-anthrylcarbinol derivatives as chiral auxiliaries. II. Asymmetric 1,3-dipolar cycloaddition

A. Carrière; A. Virgili; M. Figueredo

doi:10.1016/0957-4166(96)00364-3

Use of 9-anthrylcarbinol derivatives as chiral auxiliaries. II. Asymmetric 1,3-dipolar cycloaddition

A. Carrière, A. Virgili, M. Figueredo

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

18 Citations (Scopus)

Abstract

The 1,3-dipolar cycloaddition of acrylates derived from 9-anthrylcarbinol to a cyclic nitrone is studied. The composition of the reaction product depends on the steric hindrance of the substituent. A complete study of the diastereoisomers was performed by NMR and we were thus able to determine the absolute configuration of the major adducts.

Original language	English
Pages (from-to)	2793-2796
Journal	Tetrahedron Asymmetry
Volume	7
Issue number	10
DOIs	https://doi.org/10.1016/0957-4166(96)00364-3
Publication status	Published - 1 Jan 1996

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abstract = "The 1,3-dipolar cycloaddition of acrylates derived from 9-anthrylcarbinol to a cyclic nitrone is studied. The composition of the reaction product depends on the steric hindrance of the substituent. A complete study of the diastereoisomers was performed by NMR and we were thus able to determine the absolute configuration of the major adducts.",

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AB - The 1,3-dipolar cycloaddition of acrylates derived from 9-anthrylcarbinol to a cyclic nitrone is studied. The composition of the reaction product depends on the steric hindrance of the substituent. A complete study of the diastereoisomers was performed by NMR and we were thus able to determine the absolute configuration of the major adducts.

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