Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]

Dolores Montllo, Joan Suades, Maria Rosario Torres, Aurea Perales, René Mathieu

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The reaction of Ph2P(C≡CR) (R = Ph, Me) with [PPh 4][HFe3(CO)11] at 58°C (R = Me) or 102°C (R = Ph) leads to the formation of [PPh4][Fe 3(CO)9(μ3-PhPCR=CPhH)], the X-ray crystal structure of which has been determined for R = Me.
Original languageEnglish
Pages (from-to)97-98
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
Publication statusPublished - 1 Jan 1989

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