Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]

Dolores Montllo; Joan Suades; Maria Rosario Torres; Aurea Perales; René Mathieu

doi:10.1039/C39890000097

Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]

Dolores Montllo, Joan Suades, Maria Rosario Torres, Aurea Perales, René Mathieu

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The reaction of Ph2P(C≡CR) (R = Ph, Me) with [PPh 4][HFe3(CO)11] at 58°C (R = Me) or 102°C (R = Ph) leads to the formation of [PPh4][Fe 3(CO)9(μ3-PhPCR=CPhH)], the X-ray crystal structure of which has been determined for R = Me.

Original language	English
Pages (from-to)	97-98
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39890000097
Publication status	Published - 1 Jan 1989

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Montllo, D., Suades, J., Torres, M. R., Perales, A., & Mathieu, R. (1989). Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]. Journal of the Chemical Society D: Chemical Communications, (2), 97-98. https://doi.org/10.1039/C39890000097

Montllo, Dolores ; Suades, Joan ; Torres, Maria Rosario ; Perales, Aurea ; Mathieu, René. / Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]. In: Journal of the Chemical Society D: Chemical Communications. 1989 ; No. 2. pp. 97-98.

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title = "Unprecedented rearrangement of phosphino alkynes Ph2P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh4][HFe3(CO)11]",

abstract = "The reaction of Ph2P(C≡CR) (R = Ph, Me) with [PPh 4][HFe3(CO)11] at 58°C (R = Me) or 102°C (R = Ph) leads to the formation of [PPh4][Fe 3(CO)9(μ3-PhPCR=CPhH)], the X-ray crystal structure of which has been determined for R = Me.",

author = "Dolores Montllo and Joan Suades and Torres, {Maria Rosario} and Aurea Perales and Ren{\'e} Mathieu",

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Montllo, D, Suades, J, Torres, MR, Perales, A & Mathieu, R 1989, 'Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]', Journal of the Chemical Society D: Chemical Communications, no. 2, pp. 97-98. https://doi.org/10.1039/C39890000097

Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]. / Montllo, Dolores; Suades, Joan; Torres, Maria Rosario; Perales, Aurea; Mathieu, René.

In: Journal of the Chemical Society D: Chemical Communications, No. 2, 01.01.1989, p. 97-98.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Unprecedented rearrangement of phosphino alkynes Ph2P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh4][HFe3(CO)11]

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AU - Suades, Joan

AU - Torres, Maria Rosario

AU - Perales, Aurea

AU - Mathieu, René

PY - 1989/1/1

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N2 - The reaction of Ph2P(C≡CR) (R = Ph, Me) with [PPh 4][HFe3(CO)11] at 58°C (R = Me) or 102°C (R = Ph) leads to the formation of [PPh4][Fe 3(CO)9(μ3-PhPCR=CPhH)], the X-ray crystal structure of which has been determined for R = Me.

AB - The reaction of Ph2P(C≡CR) (R = Ph, Me) with [PPh 4][HFe3(CO)11] at 58°C (R = Me) or 102°C (R = Ph) leads to the formation of [PPh4][Fe 3(CO)9(μ3-PhPCR=CPhH)], the X-ray crystal structure of which has been determined for R = Me.

U2 - 10.1039/C39890000097

DO - 10.1039/C39890000097

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Montllo D, Suades J, Torres MR, Perales A, Mathieu R. Unprecedented rearrangement of phosphino alkynes Ph<inf>2</inf>P(C≡ CR) (R = Ph, Me) into bridging vinyl phosphido ligands PhP(CR=CPhH) during the reaction with [PPh<inf>4</inf>][HFe<inf>3</inf>(CO)<inf>11</inf>]. Journal of the Chemical Society D: Chemical Communications. 1989 Jan 1;(2):97-98. https://doi.org/10.1039/C39890000097