Unprecedented acid-catalyzed Wurtz-type coupling of meso-bromoindodicarbocyanine dyes

Sergey Miltsov, Vladimir Karavan, Alexandr Misharev, Galina Starova, Julian Alonso-Chamarro, Mar Puyol

Research output: Contribution to journalArticleResearchpeer-review

4 Citations (Scopus)

Abstract

© 2017 Elsevier Ltd meso-Bromosubstituted indodicarbocyanine dyes produce dimeric molecules, together with the debrominated species, under acid catalysis. The relationship between the dimerization and hydrodebromination routes depends on the aryl substitution of the dyes. A possible reaction mechanism is also proposed.
Original languageEnglish
Pages (from-to)3353-3357
JournalTetrahedron Letters
Volume58
Issue number34
DOIs
Publication statusPublished - 1 Jan 2017

Keywords

  • Acid catalysis
  • Boron trifluoride
  • Cyanine dyes
  • Dimerization
  • Mechanism

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