TY - JOUR
T1 - Understanding specific effects on the standard potential shifts of electrogenerated species in 1-butyl-3-methylimidazolium ionic liquids
AU - Cruz, Hugo
AU - Gallardo, Iluminada
AU - Guirado, Gonzalo
PY - 2008/8/20
Y1 - 2008/8/20
N2 - It has been established that the dependence of the E° values in function of the electrochemical media selected for a large amount of reversible redox probes in reduction and also in oxidation. For such a purpose several electroactive substances either in reduction (4-nitrotoluene, 1,3-dinitrobenzene, tetrakis(dimethylamino)ethylene, 1,3,5-trinitrobenzene, and 2,4,6-trinitroanisole) or oxidation (ferrocene, tetrathiofulvalene, tris-4-bromophenylamine, tris-4-tolylamine, and N,N,N′,N′-tetramethyl-para-phenylenediamine) have been studied in aprotic RTILs based on unsymmetrical organic cations (quaternary ammonium cations, such as 1-butyl-3-methyl imidazolium) and a weakly coordinating inorganic anion (anions with low Lewis basicities, e.g., BF4, PF6). Ion-pairing effects between imidazolium ions and anions and dianions for the electrochemically generated species, the solvation differences between BF4-/PF6- cations and dications as well as some different reaction mechanism pathways followed by these electrogenerated species in function of the solvent have also been carefully examined. © 2008 Elsevier Ltd. All rights reserved.
AB - It has been established that the dependence of the E° values in function of the electrochemical media selected for a large amount of reversible redox probes in reduction and also in oxidation. For such a purpose several electroactive substances either in reduction (4-nitrotoluene, 1,3-dinitrobenzene, tetrakis(dimethylamino)ethylene, 1,3,5-trinitrobenzene, and 2,4,6-trinitroanisole) or oxidation (ferrocene, tetrathiofulvalene, tris-4-bromophenylamine, tris-4-tolylamine, and N,N,N′,N′-tetramethyl-para-phenylenediamine) have been studied in aprotic RTILs based on unsymmetrical organic cations (quaternary ammonium cations, such as 1-butyl-3-methyl imidazolium) and a weakly coordinating inorganic anion (anions with low Lewis basicities, e.g., BF4, PF6). Ion-pairing effects between imidazolium ions and anions and dianions for the electrochemically generated species, the solvation differences between BF4-/PF6- cations and dications as well as some different reaction mechanism pathways followed by these electrogenerated species in function of the solvent have also been carefully examined. © 2008 Elsevier Ltd. All rights reserved.
KW - Electrochemistry
KW - Ion-pairing effects
KW - Ionic liquids
KW - Redox probes
KW - Solvation effects
U2 - 10.1016/j.electacta.2008.03.062
DO - 10.1016/j.electacta.2008.03.062
M3 - Article
VL - 53
SP - 5968
EP - 5976
JO - Electrochimica Acta
JF - Electrochimica Acta
SN - 0013-4686
IS - 20
ER -