Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels

Laura Martín; Elies Molins; Adelina Vallribera

doi:10.1039/c6nj02279k

Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels

Laura Martín, Elies Molins, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The application of a positive electric field on a Pd(0)-carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki-Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.

Original language	English
Pages (from-to)	10208-10212
Journal	New Journal of Chemistry
Volume	40
Issue number	12
DOIs	https://doi.org/10.1039/c6nj02279k
Publication status	Published - 1 Jan 2016

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title = "Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels",

abstract = "{\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The application of a positive electric field on a Pd(0)-carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki-Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.",

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T1 - Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels

AU - Martín, Laura

AU - Molins, Elies

AU - Vallribera, Adelina

PY - 2016/1/1

Y1 - 2016/1/1

N2 - © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The application of a positive electric field on a Pd(0)-carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki-Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.

AB - © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The application of a positive electric field on a Pd(0)-carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki-Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.

U2 - 10.1039/c6nj02279k

DO - 10.1039/c6nj02279k

M3 - Article

VL - 40

SP - 10208

EP - 10212

IS - 12

ER -

Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels

Abstract

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