Tuning and enhancement of the Mizoroki-Heck reaction using polarized Pd nanocomposite carbon aerogels

Laura Martín, Elies Molins, Adelina Vallribera

Research output: Contribution to journalArticleResearchpeer-review

5 Citations (Scopus)

Abstract

© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The application of a positive electric field on a Pd(0)-carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki-Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.
Original languageEnglish
Pages (from-to)10208-10212
JournalNew Journal of Chemistry
Volume40
Issue number12
DOIs
Publication statusPublished - 1 Jan 2016

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