TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

Manuel Souto; Concepció Rovira; Imma Ratera; Jaume Veciana

doi:10.1039/C6CE01660J

TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

Manuel Souto, Concepció Rovira, Imma Ratera, Jaume Veciana

Research output: Contribution to journal › Review article › Research › peer-review

11 Citations (Scopus)

Abstract

© The Royal Society of Chemistry. Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.

Original language	English
Pages (from-to)	197-206
Journal	CrystEngComm
Volume	19
Issue number	2
DOIs	https://doi.org/10.1039/C6CE01660J
Publication status	Published - 1 Jan 2017

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title = "TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state",

abstract = "{\textcopyright} The Royal Society of Chemistry. Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.",

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T1 - TTF-PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state

AU - Souto, Manuel

AU - Rovira, Concepció

AU - Ratera, Imma

AU - Veciana, Jaume

PY - 2017/1/1

Y1 - 2017/1/1

N2 - © The Royal Society of Chemistry. Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.

AB - © The Royal Society of Chemistry. Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor perchlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we examine the self-assembling properties of different TTF-π-PTM radical dyads that have potential applications as molecular switches or conductors in the field of molecular electronics.

U2 - 10.1039/C6CE01660J

DO - 10.1039/C6CE01660J

M3 - Review article

VL - 19

SP - 197

EP - 206

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 2

ER -