Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts

Anna Serra-Muns; Roser Pleixats

doi:10.1016/j.jorganchem.2010.01.033

Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts

Anna Serra-Muns, Roser Pleixats

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The allylation of several nitrogen and oxygen based nucleophiles with ethyl cinnamyl carbonate under mild conditions is described. The processes take place in the absence of added base and in the presence of the precatalytic system Pd(0)-triolefinic macrocycle/1,1′-bis(diphenylphosphino)ferrocene. The macrocyclic ligand plays a key role in the recovery of the metal in the form of the initial macrocyclic complex. © 2010 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1231-1236
Journal	Journal of Organometallic Chemistry
Volume	695
Issue number	8
DOIs	https://doi.org/10.1016/j.jorganchem.2010.01.033
Publication status	Published - 15 Apr 2010

Keywords

Allylation
Catalysis
Macrocyclic ligands
Olefin complex
Palladium

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title = "Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts",

abstract = "The allylation of several nitrogen and oxygen based nucleophiles with ethyl cinnamyl carbonate under mild conditions is described. The processes take place in the absence of added base and in the presence of the precatalytic system Pd(0)-triolefinic macrocycle/1,1′-bis(diphenylphosphino)ferrocene. The macrocyclic ligand plays a key role in the recovery of the metal in the form of the initial macrocyclic complex. {\textcopyright} 2010 Elsevier B.V. All rights reserved.",

keywords = "Allylation, Catalysis, Macrocyclic ligands, Olefin complex, Palladium",

author = "Anna Serra-Muns and Roser Pleixats",

year = "2010",

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doi = "10.1016/j.jorganchem.2010.01.033",

language = "English",

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T1 - Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts

AU - Serra-Muns, Anna

AU - Pleixats, Roser

PY - 2010/4/15

Y1 - 2010/4/15

N2 - The allylation of several nitrogen and oxygen based nucleophiles with ethyl cinnamyl carbonate under mild conditions is described. The processes take place in the absence of added base and in the presence of the precatalytic system Pd(0)-triolefinic macrocycle/1,1′-bis(diphenylphosphino)ferrocene. The macrocyclic ligand plays a key role in the recovery of the metal in the form of the initial macrocyclic complex. © 2010 Elsevier B.V. All rights reserved.

AB - The allylation of several nitrogen and oxygen based nucleophiles with ethyl cinnamyl carbonate under mild conditions is described. The processes take place in the absence of added base and in the presence of the precatalytic system Pd(0)-triolefinic macrocycle/1,1′-bis(diphenylphosphino)ferrocene. The macrocyclic ligand plays a key role in the recovery of the metal in the form of the initial macrocyclic complex. © 2010 Elsevier B.V. All rights reserved.

KW - Allylation

KW - Catalysis

KW - Macrocyclic ligands

KW - Olefin complex

KW - Palladium

U2 - 10.1016/j.jorganchem.2010.01.033

DO - 10.1016/j.jorganchem.2010.01.033

M3 - Article

VL - 695

SP - 1231

EP - 1236

IS - 8

ER -