Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts

Anna Serra-Muns, Roser Pleixats

Research output: Contribution to journalArticleResearchpeer-review

11 Citations (Scopus)

Abstract

The allylation of several nitrogen and oxygen based nucleophiles with ethyl cinnamyl carbonate under mild conditions is described. The processes take place in the absence of added base and in the presence of the precatalytic system Pd(0)-triolefinic macrocycle/1,1′-bis(diphenylphosphino)ferrocene. The macrocyclic ligand plays a key role in the recovery of the metal in the form of the initial macrocyclic complex. © 2010 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)1231-1236
JournalJournal of Organometallic Chemistry
Volume695
Issue number8
DOIs
Publication statusPublished - 15 Apr 2010

Keywords

  • Allylation
  • Catalysis
  • Macrocyclic ligands
  • Olefin complex
  • Palladium

Fingerprint Dive into the research topics of 'Tsuji-Trost allylations with palladium recovery by phosphines/Pd(0)-triolefinic macrocyclic catalysts'. Together they form a unique fingerprint.

Cite this