Transition metal complexes with 1-methyl-4,4-dimercaptopiperidine

H. Barrera, F. Teixidor

    Research output: Contribution to journalArticleResearchpeer-review

    3 Citations (Scopus)

    Abstract

    The syntheses of Co(AH2)2X2 (AH2 = 1-methyl-4, 4-dimercaptopiperidine, X = Cl Br, I, acetate, propanate, perchlorate, nitrate and sulphate), M(AH2) Cl2 (M = Cd, Zn) are described. According to IR and UV-visible data it seems most probable that the aminogem-dithiol (AH2) coordinates Co via both sulphur atoms, but Zn and Cd via one sulphur. A square pyramidal geometry about Co and a tetrahedral geometry about Zn and Cd are proposed. In no case has coordination via nitrogen been found. Strong X-H...N hydrogen bonds have been observed in most of these complexes. © 1983.
    Original languageEnglish
    Pages (from-to)1165-1169
    JournalPolyhedron
    Volume2
    Issue number11
    DOIs
    Publication statusPublished - 1 Jan 1983

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