Through-space ligand interactions in enantiomeric dinuclear Ru complexes

Nora Planas, Gemma J. Christian, Elena Mas-Marzá, Xavier Sala, Xavier Fontrodona, Feliu Maseras, Antoni Llobet

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19 Citations (Scopus)

Abstract

Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish
Pages (from-to)7965-7968
JournalChemistry - A European Journal
Volume16
Issue number27
DOIs
Publication statusPublished - 19 Jul 2010

Keywords

  • N ligands
  • NMR spectroscopy
  • Ruthenium
  • Structure elucidation

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    Planas, N., Christian, G. J., Mas-Marzá, E., Sala, X., Fontrodona, X., Maseras, F., & Llobet, A. (2010). Through-space ligand interactions in enantiomeric dinuclear Ru complexes. Chemistry - A European Journal, 16(27), 7965-7968. https://doi.org/10.1002/chem.201000585