Through-space ligand interactions in enantiomeric dinuclear Ru complexes

Nora Planas; Gemma J. Christian; Elena Mas-Marzá; Xavier Sala; Xavier Fontrodona; Feliu Maseras; Antoni Llobet

doi:10.1002/chem.201000585

Through-space ligand interactions in enantiomeric dinuclear Ru complexes

Nora Planas, Gemma J. Christian, Elena Mas-Marzá, Xavier Sala, Xavier Fontrodona, Feliu Maseras, Antoni Llobet

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

22 Citations (Scopus)

Abstract

Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	7965-7968
Journal	Chemistry - A European Journal
Volume	16
Issue number	27
DOIs	https://doi.org/10.1002/chem.201000585
Publication status	Published - 19 Jul 2010

Keywords

N ligands
NMR spectroscopy
Ruthenium
Structure elucidation

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title = "Through-space ligand interactions in enantiomeric dinuclear Ru complexes",

abstract = "Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) {\textcopyright} 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

keywords = "N ligands, NMR spectroscopy, Ruthenium, Structure elucidation",

author = "Nora Planas and Christian, {Gemma J.} and Elena Mas-Marz{\'a} and Xavier Sala and Xavier Fontrodona and Feliu Maseras and Antoni Llobet",

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T1 - Through-space ligand interactions in enantiomeric dinuclear Ru complexes

AU - Planas, Nora

AU - Christian, Gemma J.

AU - Mas-Marzá, Elena

AU - Sala, Xavier

AU - Fontrodona, Xavier

AU - Maseras, Feliu

AU - Llobet, Antoni

PY - 2010/7/19

Y1 - 2010/7/19

N2 - Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru(T)(L)}2(μ-bpp)](n+1)+ (T = tridentate meridional ligand; bpp = tetradentate bridging ligand and L = monodentate ligand, n = 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - N ligands

KW - NMR spectroscopy

KW - Ruthenium

KW - Structure elucidation

U2 - 10.1002/chem.201000585

DO - 10.1002/chem.201000585

M3 - Article

SN - 0947-6539

VL - 16

SP - 7965

EP - 7968

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 27

ER -

Through-space ligand interactions in enantiomeric dinuclear Ru complexes

Abstract

Keywords

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