Thermochemical parameters of the thermal dehydration of trans-[CrF(H<inf>2</inf>O)(1,3-diaminopropane)<inf>2</inf>] [M(CN)<inf>4</inf>] (M = Pd, Pt)

M. Serra; A. Escuer; J. Ribas; M. D. Baró

doi:https://doi.org/10.1016/0040-6031(83)85001-1

Thermochemical parameters of the thermal dehydration of trans-[CrF(H<inf>2</inf>O)(1,3-diaminopropane)<inf>2</inf>] [M(CN)<inf>4</inf>] (M = Pd, Pt)

M. Serra, A. Escuer, J. Ribas, M. D. Baró

Department of Physics

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

The solid phase thermal de-aquation of trans-[CrF(H2O)(tmd)2][M(CN)4] (M=Pd, Pt) (tmd = 1,3-diaminopropane) has been investigated by means of DSC and TG measurements. The enthalpy of reaction has been determined and the activation energy has been found by non-isothermal and isothermal kinetic studies. The values found for the activation energy are low and similar to those reported for the analogous compound trans-[CrF(H2O)-(tmd) 2][Ni(CN)4] (about 120 kJ mole-1) and permit the assignment of a de-aquationanation mechanism of the SN1 type, involving penta-coordinated activated species and elimination of water as Frenkel defects. © 1993.

Original language	English
Pages (from-to)	237-246
Journal	Thermochimica Acta
Volume	64
DOIs	https://doi.org/10.1016/0040-6031(83)85001-1
Publication status	Published - 15 Jun 1983

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@article{26697fe3535942b1af6fd678469112c3,

title = "Thermochemical parameters of the thermal dehydration of trans-[CrF(H2O)(1,3-diaminopropane)2] [M(CN)4] (M = Pd, Pt)",

abstract = "The solid phase thermal de-aquation of trans-[CrF(H2O)(tmd)2][M(CN)4] (M=Pd, Pt) (tmd = 1,3-diaminopropane) has been investigated by means of DSC and TG measurements. The enthalpy of reaction has been determined and the activation energy has been found by non-isothermal and isothermal kinetic studies. The values found for the activation energy are low and similar to those reported for the analogous compound trans-[CrF(H2O)-(tmd) 2][Ni(CN)4] (about 120 kJ mole-1) and permit the assignment of a de-aquationanation mechanism of the SN1 type, involving penta-coordinated activated species and elimination of water as Frenkel defects. {\textcopyright} 1993.",

author = "M. Serra and A. Escuer and J. Ribas and Bar{\'o}, {M. D.}",

year = "1983",

month = jun,

day = "15",

doi = "https://doi.org/10.1016/0040-6031(83)85001-1",

language = "English",

volume = "64",

pages = "237--246",

journal = "Thermochimica Acta",

issn = "0040-6031",

}

TY - JOUR

T1 - Thermochemical parameters of the thermal dehydration of trans-[CrF(H2O)(1,3-diaminopropane)2] [M(CN)4] (M = Pd, Pt)

AU - Serra, M.

AU - Escuer, A.

AU - Ribas, J.

AU - Baró, M. D.

PY - 1983/6/15

Y1 - 1983/6/15

N2 - The solid phase thermal de-aquation of trans-[CrF(H2O)(tmd)2][M(CN)4] (M=Pd, Pt) (tmd = 1,3-diaminopropane) has been investigated by means of DSC and TG measurements. The enthalpy of reaction has been determined and the activation energy has been found by non-isothermal and isothermal kinetic studies. The values found for the activation energy are low and similar to those reported for the analogous compound trans-[CrF(H2O)-(tmd) 2][Ni(CN)4] (about 120 kJ mole-1) and permit the assignment of a de-aquationanation mechanism of the SN1 type, involving penta-coordinated activated species and elimination of water as Frenkel defects. © 1993.

AB - The solid phase thermal de-aquation of trans-[CrF(H2O)(tmd)2][M(CN)4] (M=Pd, Pt) (tmd = 1,3-diaminopropane) has been investigated by means of DSC and TG measurements. The enthalpy of reaction has been determined and the activation energy has been found by non-isothermal and isothermal kinetic studies. The values found for the activation energy are low and similar to those reported for the analogous compound trans-[CrF(H2O)-(tmd) 2][Ni(CN)4] (about 120 kJ mole-1) and permit the assignment of a de-aquationanation mechanism of the SN1 type, involving penta-coordinated activated species and elimination of water as Frenkel defects. © 1993.

U2 - https://doi.org/10.1016/0040-6031(83)85001-1

DO - https://doi.org/10.1016/0040-6031(83)85001-1

M3 - Article

VL - 64

SP - 237

EP - 246

JO - Thermochimica Acta

JF - Thermochimica Acta

SN - 0040-6031

ER -