Theoretical interpretation of experimental data on 1,3-dipolar cycloadditions

J. M. Lluch, J. Bertrán

Research output: Contribution to journalArticleResearchpeer-review

11 Citations (Scopus)

Abstract

Using the MINDO/3 method it has been shown that the two-steps mechanism, proposed in a previous paper1 for the 1,3-dipolar cycladditions, is compatible with several existing experimental results. Firstly, the effects of the introduction of different substituents on the mechanism of the cycloadditions were studied. Secondly, the slight influence of the polarity of the solvent on the reaction rate has been interpreted by solvation calculations. Finally, the stereospecificity observed has been explained. © 1982.
Original languageEnglish
Pages (from-to)1847-1852
JournalTetrahedron
Volume38
Issue number12
DOIs
Publication statusPublished - 1 Jan 1982

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