Theoretical interpretation of experimental data on 1,3-dipolar cycloadditions

J. M. Lluch; J. Bertrán

doi:10.1016/0040-4020(82)80262-7

Theoretical interpretation of experimental data on 1,3-dipolar cycloadditions

J. M. Lluch, J. Bertrán

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Abstract

Using the MINDO/3 method it has been shown that the two-steps mechanism, proposed in a previous paper1 for the 1,3-dipolar cycladditions, is compatible with several existing experimental results. Firstly, the effects of the introduction of different substituents on the mechanism of the cycloadditions were studied. Secondly, the slight influence of the polarity of the solvent on the reaction rate has been interpreted by solvation calculations. Finally, the stereospecificity observed has been explained. © 1982.

Original language	English
Pages (from-to)	1847-1852
Journal	Tetrahedron
Volume	38
Issue number	12
DOIs	https://doi.org/10.1016/0040-4020(82)80262-7
Publication status	Published - 1 Jan 1982

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title = "Theoretical interpretation of experimental data on 1,3-dipolar cycloadditions",

abstract = "Using the MINDO/3 method it has been shown that the two-steps mechanism, proposed in a previous paper1 for the 1,3-dipolar cycladditions, is compatible with several existing experimental results. Firstly, the effects of the introduction of different substituents on the mechanism of the cycloadditions were studied. Secondly, the slight influence of the polarity of the solvent on the reaction rate has been interpreted by solvation calculations. Finally, the stereospecificity observed has been explained. {\textcopyright} 1982.",

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AU - Lluch, J. M.

AU - Bertrán, J.

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Y1 - 1982/1/1

N2 - Using the MINDO/3 method it has been shown that the two-steps mechanism, proposed in a previous paper1 for the 1,3-dipolar cycladditions, is compatible with several existing experimental results. Firstly, the effects of the introduction of different substituents on the mechanism of the cycloadditions were studied. Secondly, the slight influence of the polarity of the solvent on the reaction rate has been interpreted by solvation calculations. Finally, the stereospecificity observed has been explained. © 1982.

AB - Using the MINDO/3 method it has been shown that the two-steps mechanism, proposed in a previous paper1 for the 1,3-dipolar cycladditions, is compatible with several existing experimental results. Firstly, the effects of the introduction of different substituents on the mechanism of the cycloadditions were studied. Secondly, the slight influence of the polarity of the solvent on the reaction rate has been interpreted by solvation calculations. Finally, the stereospecificity observed has been explained. © 1982.

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DO - 10.1016/0040-4020(82)80262-7

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EP - 1852

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 12

ER -

Theoretical interpretation of experimental data on 1,3-dipolar cycloadditions

Abstract

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