The search for new biochemical photoprobes. II. The nucleophilic photosubstitution of 2-fluoro-4-nitroanisole.

R. Pleixats; M. Figueredo; J. Marquet; M. Moreno-Mañas; A. Cantos

doi:10.1016/S0040-4020(01)85796-3

The search for new biochemical photoprobes. II. The nucleophilic photosubstitution of 2-fluoro-4-nitroanisole.

R. Pleixats, M. Figueredo, J. Marquet, M. Moreno-Mañas, A. Cantos

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

The photosubstitutions of 2-fluoro-4-nitroanisole with several amines are studied. The preparative results, the thermal stability of the photochemical substrate, and the limiting quantum yield values obtained from photoreactions with several nucleophiles suggest the possible usefulness of 2-fluoro-4-nitrophenyl ethers as biochemical photoprobes. © 1989.

Original language	English
Pages (from-to)	7817-7826
Journal	Tetrahedron
Volume	45
Issue number	24
DOIs	https://doi.org/10.1016/S0040-4020(01)85796-3
Publication status	Published - 1 Jan 1989

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Pleixats, R., Figueredo, M., Marquet, J., Moreno-Mañas, M., & Cantos, A. (1989). The search for new biochemical photoprobes. II. The nucleophilic photosubstitution of 2-fluoro-4-nitroanisole. Tetrahedron, 45(24), 7817-7826. https://doi.org/10.1016/S0040-4020(01)85796-3

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AB - The photosubstitutions of 2-fluoro-4-nitroanisole with several amines are studied. The preparative results, the thermal stability of the photochemical substrate, and the limiting quantum yield values obtained from photoreactions with several nucleophiles suggest the possible usefulness of 2-fluoro-4-nitrophenyl ethers as biochemical photoprobes. © 1989.

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