The role of solvation in redox processes

Ferran Sanz; Joan Bertran

doi:10.1016/0009-2614(79)80170-0

The role of solvation in redox processes

Ferran Sanz, Joan Bertran

Department of Paediatrics, Obstetrics and Gynaecology and Preventive Medicine and Public Health

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN--H2O. We define as "efficient" those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the "stable" anions and cations. © 1979.

Original language	English
Pages (from-to)	255-258
Journal	Chemical Physics Letters
Volume	62
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(79)80170-0
Publication status	Published - 1 Apr 1979

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title = "The role of solvation in redox processes",

abstract = "In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN--H2O. We define as {"}efficient{"} those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the {"}stable{"} anions and cations. {\textcopyright} 1979.",

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T1 - The role of solvation in redox processes

AU - Sanz, Ferran

AU - Bertran, Joan

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N2 - In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN--H2O. We define as "efficient" those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the "stable" anions and cations. © 1979.

AB - In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN--H2O. We define as "efficient" those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the "stable" anions and cations. © 1979.

U2 - 10.1016/0009-2614(79)80170-0

DO - 10.1016/0009-2614(79)80170-0

M3 - Article

VL - 62

SP - 255

EP - 258

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 2

ER -