Abstract
In studying the role of solvation in redox processes we consider the influence of geometrical modifications in the discharge of monosolvated anion CN--H2O. We define as "efficient" those modifications whose energy cost is less than the lowering which is produced in the ionization potential. we conclude that in the above-mentioned species the redox process is enhanced by desolvation. We try to generalise the results for the "stable" anions and cations. © 1979.
Original language | English |
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Pages (from-to) | 255-258 |
Journal | Chemical Physics Letters |
Volume | 62 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1 Apr 1979 |