The nucleophilic aromatic photosubstitution in photoaffinity labelling. A model study of a cycloheximide derivative.

A. Castelló, J. Marquet, M. Moreno-Mañas, X. Sirera

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

The photoreactions of several 4-nitrocatechol ethers with the relatively hard nucleophile methylamine occurs at the meta position respect to the nitro group. A derivative of the antibiotic cycloheximide carrying a 4-nitrocatechol ether moiety reacts with methylamine affording an in vitro model for photoaffinity labelling. © 1985.
Original languageEnglish
Pages (from-to)2489-2492
JournalTetrahedron Letters
Volume26
Issue number20
DOIs
Publication statusPublished - 1 Jan 1985

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