The Ni-mediated cyclocarbonylation of allyl halides and alkynes made catalytic. Evidence supporting the involvement of pseudoradical NiI species in the mechanism

M. Lluïsa Nadal, Julia Bosch, Josep M. Vila, Günter Klein, Susagna Ricart, Josep M. Moretó

    Research output: Contribution to journalArticleResearchpeer-review

    26 Citations (Scopus)

    Abstract

    We report here on a highly efficient catalytic method to synthesize intermolecularly the cyclopentane skeleton from starting products as simple as allyl halides, alkynes, and carbon monoxide under very mild reaction conditions by means of a substoichiometric amount of iron, acetone, and a catalytic amount of Ni(II) iodide. Copyright © 2005 American Chemical Society.
    Original languageEnglish
    Pages (from-to)10476-10477
    JournalJournal of the American Chemical Society
    Volume127
    Issue number30
    DOIs
    Publication statusPublished - 3 Aug 2005

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