The formation of [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (Me2HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me2Pz)Ph2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me2 HPz)(PPh2OH)]Cl

Rosa Tribó; Josefina Pons; Ramón Yáñez; Joan F. Piniella; Ángel Alvarez-Larena; Josep Ros

doi:10.1016/S1387-7003(00)00135-0

The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl

Rosa Tribó, Josefina Pons, Ramón Yáñez, Joan F. Piniella, Ángel Alvarez-Larena, Josep Ros

Research output: Contribution to journal › Article › Research › peer-review

33 Citations (Scopus)

Abstract

The complex [RuCl2(p-cymene)]2 reacts with 1-(3,5-dimethyl)pyrazolyldiphenylphosphine (P(Me2Pz)Ph2) to give the complex RuCl2(p-cymene)(P(Me2Pz)Ph2). This compound reacts with ROH molecules (R = H, Me and p-Tol) to give [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (R = H, Me and p-Tol) complexes, which contain both Me2HPz and PPh2OR coordinated molecules. (C) 2000 Published by Elsevier Science S.A.

Original language	English
Pages (from-to)	545-549
Journal	Inorganic Chemistry Communications
Volume	3
Issue number	10
DOIs	https://doi.org/10.1016/S1387-7003(00)00135-0
Publication status	Published - 17 Oct 2000

Keywords

Pyrazoles
Pyrazolyl-phosphine ligands
Ruthenium complexes
Ruthenium-arene complexes

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10.1016/S1387-7003(00)00135-0

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Tribó, R., Pons, J., Yáñez, R., Piniella, J. F., Alvarez-Larena, Á., & Ros, J. (2000). The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl. Inorganic Chemistry Communications, 3(10), 545-549. https://doi.org/10.1016/S1387-7003(00)00135-0

Tribó, Rosa ; Pons, Josefina ; Yáñez, Ramón et al. / The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl. In: Inorganic Chemistry Communications. 2000 ; Vol. 3, No. 10. pp. 545-549.

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title = "The formation of [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (Me2HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me2Pz)Ph2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me2 HPz)(PPh2OH)]Cl",

abstract = "The complex [RuCl2(p-cymene)]2 reacts with 1-(3,5-dimethyl)pyrazolyldiphenylphosphine (P(Me2Pz)Ph2) to give the complex RuCl2(p-cymene)(P(Me2Pz)Ph2). This compound reacts with ROH molecules (R = H, Me and p-Tol) to give [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (R = H, Me and p-Tol) complexes, which contain both Me2HPz and PPh2OR coordinated molecules. (C) 2000 Published by Elsevier Science S.A.",

keywords = "Pyrazoles, Pyrazolyl-phosphine ligands, Ruthenium complexes, Ruthenium-arene complexes",

author = "Rosa Trib{\'o} and Josefina Pons and Ram{\'o}n Y{\'a}{\~n}ez and Piniella, {Joan F.} and {\'A}ngel Alvarez-Larena and Josep Ros",

year = "2000",

month = oct,

day = "17",

doi = "10.1016/S1387-7003(00)00135-0",

language = "English",

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pages = "545--549",

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Tribó, R, Pons, J , Yáñez, R , Piniella, JF, Alvarez-Larena, Á & Ros, J 2000, 'The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl', Inorganic Chemistry Communications, vol. 3, no. 10, pp. 545-549. https://doi.org/10.1016/S1387-7003(00)00135-0

The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl. / Tribó, Rosa; Pons, Josefina ; Yáñez, Ramón et al.
In: Inorganic Chemistry Communications, Vol. 3, No. 10, 17.10.2000, p. 545-549.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - The formation of [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (Me2HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me2Pz)Ph2 ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me2 HPz)(PPh2OH)]Cl

AU - Tribó, Rosa

AU - Pons, Josefina

AU - Yáñez, Ramón

AU - Piniella, Joan F.

AU - Alvarez-Larena, Ángel

AU - Ros, Josep

PY - 2000/10/17

Y1 - 2000/10/17

N2 - The complex [RuCl2(p-cymene)]2 reacts with 1-(3,5-dimethyl)pyrazolyldiphenylphosphine (P(Me2Pz)Ph2) to give the complex RuCl2(p-cymene)(P(Me2Pz)Ph2). This compound reacts with ROH molecules (R = H, Me and p-Tol) to give [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (R = H, Me and p-Tol) complexes, which contain both Me2HPz and PPh2OR coordinated molecules. (C) 2000 Published by Elsevier Science S.A.

AB - The complex [RuCl2(p-cymene)]2 reacts with 1-(3,5-dimethyl)pyrazolyldiphenylphosphine (P(Me2Pz)Ph2) to give the complex RuCl2(p-cymene)(P(Me2Pz)Ph2). This compound reacts with ROH molecules (R = H, Me and p-Tol) to give [RuCl(p-cymene)(Me2HPz)(PPh2OR)]Cl (R = H, Me and p-Tol) complexes, which contain both Me2HPz and PPh2OR coordinated molecules. (C) 2000 Published by Elsevier Science S.A.

KW - Pyrazoles

KW - Pyrazolyl-phosphine ligands

KW - Ruthenium complexes

KW - Ruthenium-arene complexes

U2 - 10.1016/S1387-7003(00)00135-0

DO - 10.1016/S1387-7003(00)00135-0

M3 - Article

SN - 1387-7003

VL - 3

SP - 545

EP - 549

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Tribó R, Pons J , Yáñez R , Piniella JF, Alvarez-Larena Á, Ros J. The formation of [RuCl(p-cymene)(Me₂HPz)(PPh₂OR)]Cl (Me₂HPz = 3, 5-dimethylpyrazole; R = H, me and p-Tol) complexes from the cleavage of the P-N bond of a P-coordinated P(Me₂Pz)Ph₂ ligand by ROH molecules in a ruthenium(II) complex. Crystal structure of [RuCl(p-cymene) (Me₂ HPz)(PPh₂OH)]Cl. Inorganic Chemistry Communications. 2000 Oct 17;3(10):545-549. doi: 10.1016/S1387-7003(00)00135-0