The first transition metal complexes of 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene complexes of palladium(0), platinum(0), and silver(I)

Silvia Cerezo, Jordi Cortès, Elena Lago, Elies Molins, Marcial Moreno-Mañas, Teodor Parella, Roser Pleixats, Javier Torrejón, Adelina Vallribera

Research output: Contribution to journalArticleResearchpeer-review

28 Citations (Scopus)

Abstract

(E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13- trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes with AgI. The three olefins in the macrocycle are responsible for the complexation. The X-ray structures of two complexes of Pd0 and Pt0 are presented; both complexes are planar trigonal. © Wiley-VCH Verlag GmbH, 2001.
Original languageEnglish
Pages (from-to)1999-2006
JournalEur. J. Inorg. Chem.
Issue number8
DOIs
Publication statusPublished - 1 Jan 2001

Keywords

  • Heterocycles
  • Macrocyclic ligands
  • Palladium
  • Platinum
  • Silver

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