The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines

Sandro Cacchi; Giancarlo Fabrizi; Antonella Goggiamani; Marcial Moreno-Manñas; Adelina Vallribera

doi:10.1016/S0040-4039(02)01120-6

The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines

Sandro Cacchi, Giancarlo Fabrizi, Antonella Goggiamani, Marcial Moreno-Manñas, Adelina Vallribera

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

49 Citations (Scopus)

Abstract

The hydroarylation of alkynes can be successfully conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4) in the presence of the [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex. The catalytic ionic solution can be recycled for reuse in subsequent reaction runs. The procedure has been applied to the preparation of 3-arylquinolines through a domino hydroarylation/cyclization process. © 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	5537-5540
Journal	Tetrahedron Letters
Volume	43
Issue number	32
DOIs	https://doi.org/10.1016/S0040-4039(02)01120-6
Publication status	Published - 5 Aug 2002

Keywords

Hydroarylation
Ionic liquids
Macrocyclic ligands
Palladium
Quinolines

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10.1016/S0040-4039(02)01120-6

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title = "The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines",

abstract = "The hydroarylation of alkynes can be successfully conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4) in the presence of the [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex. The catalytic ionic solution can be recycled for reuse in subsequent reaction runs. The procedure has been applied to the preparation of 3-arylquinolines through a domino hydroarylation/cyclization process. {\textcopyright} 2002 Elsevier Science Ltd. All rights reserved.",

keywords = "Hydroarylation, Ionic liquids, Macrocyclic ligands, Palladium, Quinolines",

author = "Sandro Cacchi and Giancarlo Fabrizi and Antonella Goggiamani and Marcial Moreno-Man{\~n}as and Adelina Vallribera",

year = "2002",

month = aug,

day = "5",

doi = "10.1016/S0040-4039(02)01120-6",

language = "English",

volume = "43",

pages = "5537--5540",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "32",

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The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines. / Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella et al.

In: Tetrahedron Letters, Vol. 43, No. 32, 05.08.2002, p. 5537-5540.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines

AU - Cacchi, Sandro

AU - Fabrizi, Giancarlo

AU - Goggiamani, Antonella

AU - Moreno-Manñas, Marcial

AU - Vallribera, Adelina

PY - 2002/8/5

Y1 - 2002/8/5

N2 - The hydroarylation of alkynes can be successfully conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4) in the presence of the [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex. The catalytic ionic solution can be recycled for reuse in subsequent reaction runs. The procedure has been applied to the preparation of 3-arylquinolines through a domino hydroarylation/cyclization process. © 2002 Elsevier Science Ltd. All rights reserved.

AB - The hydroarylation of alkynes can be successfully conducted in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4) in the presence of the [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex. The catalytic ionic solution can be recycled for reuse in subsequent reaction runs. The procedure has been applied to the preparation of 3-arylquinolines through a domino hydroarylation/cyclization process. © 2002 Elsevier Science Ltd. All rights reserved.

KW - Hydroarylation

KW - Ionic liquids

KW - Macrocyclic ligands

KW - Palladium

KW - Quinolines

U2 - 10.1016/S0040-4039(02)01120-6

DO - 10.1016/S0040-4039(02)01120-6

M3 - Article

VL - 43

SP - 5537

EP - 5540

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 32

ER -

The [(E, E, E)-1,6,11-tris(p-toluenesulfonyl)-1,6,11-triazacyclopentadeca-3,8, 13-triene]Pd(0) complex in the hydroarylation of alkynes in ionic liquids. An approach to quinolines

Abstract

Keywords

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