TY - JOUR
T1 - The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol
AU - Estivill, Carla
AU - Pomares, Marta
AU - Kotev, Martin
AU - Ivanov, Petko
AU - Virgili, Albert
PY - 2005/9/19
Y1 - 2005/9/19
N2 - The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.
AB - The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.
U2 - 10.1016/j.tetasy.2005.08.011
DO - 10.1016/j.tetasy.2005.08.011
M3 - Article
SN - 0957-4166
VL - 16
SP - 2993
EP - 2997
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 18
ER -