The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol

Carla Estivill, Marta Pomares, Martin Kotev, Petko Ivanov, Albert Virgili

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)2993-2997
JournalTetrahedron Asymmetry
Volume16
Issue number18
DOIs
Publication statusPublished - 19 Sep 2005

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