Abstract
The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.
Original language | English |
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Pages (from-to) | 2993-2997 |
Journal | Tetrahedron Asymmetry |
Volume | 16 |
Issue number | 18 |
DOIs | |
Publication status | Published - 19 Sep 2005 |