The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol

Carla Estivill; Marta Pomares; Martin Kotev; Petko Ivanov; Albert Virgili

doi:10.1016/j.tetasy.2005.08.011

The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol

Carla Estivill, Marta Pomares, Martin Kotev, Petko Ivanov, Albert Virgili

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2993-2997
Journal	Tetrahedron Asymmetry
Volume	16
Issue number	18
DOIs	https://doi.org/10.1016/j.tetasy.2005.08.011
Publication status	Published - 19 Sep 2005

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title = "The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol",

abstract = "The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. {\textcopyright} 2005 Elsevier Ltd. All rights reserved.",

author = "Carla Estivill and Marta Pomares and Martin Kotev and Petko Ivanov and Albert Virgili",

year = "2005",

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doi = "10.1016/j.tetasy.2005.08.011",

language = "English",

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TY - JOUR

T1 - The bidentate complexes of (R,R)- and meso-α,α′- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol

AU - Estivill, Carla

AU - Pomares, Marta

AU - Kotev, Martin

AU - Ivanov, Petko

AU - Virgili, Albert

PY - 2005/9/19

Y1 - 2005/9/19

N2 - The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.

AB - The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-α,α′-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species. © 2005 Elsevier Ltd. All rights reserved.

U2 - 10.1016/j.tetasy.2005.08.011

DO - 10.1016/j.tetasy.2005.08.011

M3 - Article

VL - 16

SP - 2993

EP - 2997

IS - 18

ER -