The 8: 1: 1 ternary hybrid framework in the system [EDT-TTF <sup>•+</sup>][1,4-bis(iodoethynyl)benzene][Re<inf>6</inf>Se <inf>8</inf>(CN)<inf>6</inf>]<sup>4-</sup>: Dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode

Anne Lise Barrès, Abdelkrim El-Ghayoury, Leokadiya V. Zorina, Enric Canadell, Pascale Auban-Senzier, Patrick Batail

    Research output: Contribution to journalArticleResearchpeer-review

    28 Citations (Scopus)

    Abstract

    Complementary shapes of the neutral symmetrical halogen-bond bis-donor core and octahedral inorganic cluster core prevent halogen-bonded polymers developing in more than one direction, favouring further templating by conducting radical cation slabs and yielding an 8: 1: 1 phase formulation instead of n: 2: 1, with a 2D net, or m: 3: 1, with a pseudo-cubic architecture, which may in principle also be targeted. © The Royal Society of Chemistry.
    Original languageEnglish
    Pages (from-to)2194-2196
    JournalChemical Communications
    Issue number19
    DOIs
    Publication statusPublished - 1 Jan 2008

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