Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut; C. Avci-Camur; J. Troyano; A. Legrand; J. Canivet; I. Imaz; D. Maspoch; H. Reinsch; D. Farrusseng

doi:10.1039/c7ce00338b

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch, D. Farrusseng

Research output: Contribution to journal › Article › Research › peer-review

74 Citations (Scopus)

Abstract

© 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

Original language	English
Pages (from-to)	4211-4218
Journal	CrystEngComm
Volume	19
Issue number	29
DOIs	https://doi.org/10.1039/c7ce00338b
Publication status	Published - 1 Jan 2017

Access to Document

10.1039/c7ce00338b

https://ddd.uab.cat/record/239287

Cite this

@article{9581816cd5c64fee846079fe772c8beb,

title = "Systematic study of the impact of MOF densification into tablets on textural and mechanical properties",

abstract = "{\textcopyright} 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.",

author = "J. Dhainaut and C. Avci-Camur and J. Troyano and A. Legrand and J. Canivet and I. Imaz and D. Maspoch and H. Reinsch and D. Farrusseng",

year = "2017",

month = jan,

day = "1",

doi = "10.1039/c7ce00338b",

language = "English",

volume = "19",

pages = "4211--4218",

journal = "CrystEngComm",

issn = "1466-8033",

number = "29",

}

TY - JOUR

T1 - Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

AU - Dhainaut, J.

AU - Avci-Camur, C.

AU - Troyano, J.

AU - Legrand, A.

AU - Canivet, J.

AU - Imaz, I.

AU - Maspoch, D.

AU - Reinsch, H.

AU - Farrusseng, D.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - © 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

AB - © 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.

UR - https://www.scopus.com/pages/publications/85026501056

U2 - 10.1039/c7ce00338b

DO - 10.1039/c7ce00338b

M3 - Article

SN - 1466-8033

VL - 19

SP - 4211

EP - 4218

JO - CrystEngComm

JF - CrystEngComm

IS - 29

ER -

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

Abstract

Access to Document

Other files and links

Fingerprint

Cite this