Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch, D. Farrusseng

    Research output: Contribution to journalArticleResearchpeer-review

    27 Citations (Scopus)

    Abstract

    © 2017 The Royal Society of Chemistry. Four different metal-organic framework powders (UiO-66, UiO-66-NH2, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. We observe a linear relationship between densification and tensile strength for all four studied MOFs, with the slope being MOF-dependent. We also report conditions for improving significantly the volumetric uptake. Finally, we evaluated our tablets' stability over time in the presence of moisture.
    Original languageEnglish
    Pages (from-to)4211-4218
    JournalCrystEngComm
    Volume19
    Issue number29
    DOIs
    Publication statusPublished - 1 Jan 2017

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