Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C <inf>2</inf> -symmetry

Pedro De March; Marta Figueredo; Josep Font; Jordi Medrano

doi:10.1016/S0040-4020(99)00400-7

Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C <inf>2</inf> -symmetry

Pedro De March, Marta Figueredo, Josep Font, Jordi Medrano

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

Several new monoketals of p-benzoquinone with the structure of 1,3- dioxaspiro[4.5]deca-6,9-dien-8-one have been synthesised in enantiopure form by the straightforward reaction of the quinone with secondary C 2 -symmetric 1,2-diols. The preparation of two new enantiopure C 2 -1,2-glycols is also reported.

Original language	English
Pages (from-to)	7907-7914
Journal	Tetrahedron
Volume	55
Issue number	25
DOIs	https://doi.org/10.1016/S0040-4020(99)00400-7
Publication status	Published - 18 Jun 1999

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title = "Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C 2 -symmetry",

abstract = "Several new monoketals of p-benzoquinone with the structure of 1,3- dioxaspiro[4.5]deca-6,9-dien-8-one have been synthesised in enantiopure form by the straightforward reaction of the quinone with secondary C 2 -symmetric 1,2-diols. The preparation of two new enantiopure C 2 -1,2-glycols is also reported.",

author = "{De March}, Pedro and Marta Figueredo and Josep Font and Jordi Medrano",

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doi = "10.1016/S0040-4020(99)00400-7",

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T1 - Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C 2 -symmetry

AU - De March, Pedro

AU - Figueredo, Marta

AU - Font, Josep

AU - Medrano, Jordi

PY - 1999/6/18

Y1 - 1999/6/18

N2 - Several new monoketals of p-benzoquinone with the structure of 1,3- dioxaspiro[4.5]deca-6,9-dien-8-one have been synthesised in enantiopure form by the straightforward reaction of the quinone with secondary C 2 -symmetric 1,2-diols. The preparation of two new enantiopure C 2 -1,2-glycols is also reported.

AB - Several new monoketals of p-benzoquinone with the structure of 1,3- dioxaspiro[4.5]deca-6,9-dien-8-one have been synthesised in enantiopure form by the straightforward reaction of the quinone with secondary C 2 -symmetric 1,2-diols. The preparation of two new enantiopure C 2 -1,2-glycols is also reported.

U2 - 10.1016/S0040-4020(99)00400-7

DO - 10.1016/S0040-4020(99)00400-7

M3 - Article

VL - 55

SP - 7907

EP - 7914

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 25

ER -

Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C <inf>2</inf> -symmetry

Abstract

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