The compound cis-[Ni(C6F5)2(PhCN)2] has been used as the starting material for the preparation of the bimetallic complexes [(C6F5)2Ni(μ-X)2Ni(C 6F5)2]2- (X = SCN, OCN, N3), [(C6F5)2Ni(μ-SCN)2Pd(C 6F5)2]2-, [(C6F5)2Ni(μ-NCS)2Pd-(dppe)] [dppe = 1,2-bis(diphenylphosphanyl)ethane], and the trimetallic[(C6F5)2Ni(μ-NCS) 2Pd(μ-SCN)2Ni(C6F5) 2]2-. The mononuclear compounds [(C6F5)2NiLX] (L = PPh3i P(C6H4MeO-P)3i X = SCN, OCN) are obtained by reaction between [(C6F5)2Ni(&μ-X)2Ni-(C 6F5)2]2- and L. The treatment of cis-[Ni(C6F5)2(PhCN)2] with [M(SAr)2(dppe)] leads to the formation of the arylthiolate complexes [(C6F5)2Ni(μ-SAr)2M(dppe)] (Ar = Ph, C6H4Me-p, C6H4NO2-p; M = Ni, Pd, Pt). The X-ray diffraction study of [(C6F5)2Ni(μ-SPh)2Pd(dppe)] shows that both metal atoms, Ni and Pd, are coordinated in a slightly distorted square-planar geometry and the μ-thiolato groups are in the syn conformation.
|Journal||European Journal of Inorganic Chemistry|
|Publication status||Published - 1 Jan 1998|
- Crystal structures
- Nickel complexes
- Organometallic compounds
Sánchez, G., Momblona, F., Sánchez, M., Pérez, J., López, G., Casabó, J., Molins, E., & Miravitlles, C. (1998). Synthesis of Homo- and Hetero-Bimetallic Complexes Containing the Ni(C<inf>6</inf>F<inf>5</inf>)<inf>2</inf> Moiety - Crystal Structure of [(C<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ni(μ-SPh)<inf>2</inf>Pd(dppe)]. European Journal of Inorganic Chemistry, (8), 1199-1204. https://doi.org/10.1002/(SICI)1099-0682(199808)1998:8<1199::AID-EJIC1199>3.0.CO;2-K