Synthesis of chiral functionalised cyclobutylpyrrolidines and cyclobutylamino alcohols from (-)-(S)-verbenone - Applications in the stabilisation of ruthenium nanocatalysts

Jordi Aguilera, Isabelle Favier, Marta Sans, Àlex Mor, Ángel Álvarez-Larena, Ona Illa, Montserrat Gómez, Rosa M. Ortuño

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6 Citations (Scopus)

Abstract

© 2015 Wiley-VCH Verlag GmbH & Co. KGaA. Stereoselective and efficient synthetic routes to pyrrolidines and amino alcohols anchored to chiral polysubstituted cyclobutane moieties have been developed from (-)-(S)-verbenone. These original frameworks, in particular the diamines and amino alcohols, are appropriate stabilisers of metallic nanoparticles, especially for the synthesis of ruthenium nanomaterials, which found catalytic applications in the hydrogenation of arenes and nitrobenzene derivatives to afford selectively the corresponding cyclohexane or aniline derivatives.
Original languageEnglish
Pages (from-to)810-819
JournalEuropean Journal of Organic Chemistry
Volume2015
Issue number4
DOIs
Publication statusPublished - 1 Jan 2015

Keywords

  • Amino alcohols
  • Heterogeneous catalysis
  • Hydrogenation
  • Nanoparticles
  • Nitrogen heterocycles
  • Ruthenium

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