Synthesis of chiral bis-MOP-type diphosphines. Chelating effect in nickel-catalyzed phosphination

Artur R. Abreu; Andreia F. Peixoto; Ana R. Almeida; Mirtha A.O. Lourenço; Angela C.B. Neves; J. Carles Bayón; Mariette M. Pereira

doi:10.1246/cl.2013.37

Synthesis of chiral bis-MOP-type diphosphines. Chelating effect in nickel-catalyzed phosphination

Artur R. Abreu, Andreia F. Peixoto, Ana R. Almeida, Mirtha A.O. Lourenço, Angela C.B. Neves, J. Carles Bayón, Mariette M. Pereira

Department of Chemistry

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4 Citations (Scopus)

Abstract

Chiral bis-MOP-type diphosphines with alkyl and pyridyl bridges connecting the two binaphthyl units have been synthesized via [NiCl2(dppe)]-assisted phosphination of the corresponding aryl triflates. The effect of the amount of the nickel complex on the reaction yield was investigated. Catalytic and even stoichiometric amounts of the complex proved to be insufficient to promote an efficient phosphination, but the use of an excess of the metal complex provides good yields. © 2013 The Chemical Society of Japan.

Original language	English
Pages (from-to)	37-39
Journal	Chemistry Letters
Volume	42
Issue number	1
DOIs	https://doi.org/10.1246/cl.2013.37
Publication status	Published - 1 Jan 2013

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title = "Synthesis of chiral bis-MOP-type diphosphines. Chelating effect in nickel-catalyzed phosphination",

abstract = "Chiral bis-MOP-type diphosphines with alkyl and pyridyl bridges connecting the two binaphthyl units have been synthesized via [NiCl2(dppe)]-assisted phosphination of the corresponding aryl triflates. The effect of the amount of the nickel complex on the reaction yield was investigated. Catalytic and even stoichiometric amounts of the complex proved to be insufficient to promote an efficient phosphination, but the use of an excess of the metal complex provides good yields. {\textcopyright} 2013 The Chemical Society of Japan.",

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AU - Abreu, Artur R.

AU - Peixoto, Andreia F.

AU - Almeida, Ana R.

AU - Lourenço, Mirtha A.O.

AU - Neves, Angela C.B.

AU - Bayón, J. Carles

AU - Pereira, Mariette M.

PY - 2013/1/1

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N2 - Chiral bis-MOP-type diphosphines with alkyl and pyridyl bridges connecting the two binaphthyl units have been synthesized via [NiCl2(dppe)]-assisted phosphination of the corresponding aryl triflates. The effect of the amount of the nickel complex on the reaction yield was investigated. Catalytic and even stoichiometric amounts of the complex proved to be insufficient to promote an efficient phosphination, but the use of an excess of the metal complex provides good yields. © 2013 The Chemical Society of Japan.

AB - Chiral bis-MOP-type diphosphines with alkyl and pyridyl bridges connecting the two binaphthyl units have been synthesized via [NiCl2(dppe)]-assisted phosphination of the corresponding aryl triflates. The effect of the amount of the nickel complex on the reaction yield was investigated. Catalytic and even stoichiometric amounts of the complex proved to be insufficient to promote an efficient phosphination, but the use of an excess of the metal complex provides good yields. © 2013 The Chemical Society of Japan.

U2 - 10.1246/cl.2013.37

DO - 10.1246/cl.2013.37

M3 - Article

VL - 42

SP - 37

EP - 39

IS - 1

ER -

Synthesis of chiral bis-MOP-type diphosphines. Chelating effect in nickel-catalyzed phosphination

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