Synthesis of a zwitterionic P-coordinated complex with bis(diphenylphosphino)acetylene

Elmostafa Louattani, Joan Suades, K. Urtiaga, M. I. Arriortua, X. Solans

Research output: Contribution to journalArticleResearchpeer-review

20 Citations (Scopus)

Abstract

New cationic, [(Fp)Ph2PC≡CPPh2(Fp)2+ (1) and [(Fp)Ph2PC≡CPPh2]+ (2), and anionic, [Fe3(CO)9(μ3-CCH3)(Ph 2PC≡CPPh2)]- (3) and [{Fe3(CO)9μ3-CCH3)} 2(Ph2PC≡CPPh2)]2- (4), P-coordinate complexes with bis(diphenylphosphino)acetylene have been prepared. The zwitterionic P-coordinated iron complex [{Fe3(CO)9-CCH3)}Ph 2PC≡CPPh2(Fp)] (5) has been synthesized in two different ways and characterized by X-ray crystallography.
Original languageEnglish
Pages (from-to)468-471
JournalOrganometallics
Volume15
Issue number1
DOIs
Publication statusPublished - 9 Jan 1996

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