Synthesis, crystal structure, and spectroscopic characterization of af-dichloro-bd,ec-bis{μ[2-(1-methyl-2-piperidinyl)ethanethiolato]-S,N ,μ-S} dipalladium(II)

H. Barrera, J. M. Viñas, M. Font-Altaba, X. Solans

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Abstract

The reaction of 2-(1-methyl-2-piperidinyl)ethanethiol with sodium tetrachloro-palladate(II) at pH = 8 yields a yellow precipitate of formula [Pd2(C8H16NS)2Cl2 ] which crystallized in the orthorhombic space group Pcab with a = 22.050(4) Å, b = 14.644(3) Å, c = 13.834(3) Å, V = 4467(3) Å3, and Z = 8. The organic ligands chelate to one Pd atom through the S and N atoms and bridges to another Pd atom through the S atom to form a dimer in which each molecule of the organic ligand has the same chirality. IR, UV-Vis and 1H NMR spectra are presented for this compound. © 1985.
Original languageEnglish
Pages (from-to)2027-2030
JournalPolyhedron
Volume4
Issue number12
DOIs
Publication statusPublished - 1 Jan 1985

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