Abstract
The reaction of chloro[2-(phenylazo)phenyl]mercury(II) with metallic tin leads to dichlorobis[2-(phenylazo)phenyl]tin(IV) whose structure has been determined by X-ray diffraction. The tin atom is six-co-ordinated in a very distorted octahedral fashion with two cis chlorine and cis nitrogen atoms in the equatorial plane and two carbon atoms of the ortho-metallated phenyl groups considerably displaced from the trans axial position [C-Sn-C = 149.7(7)°].
Original language | English |
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Pages (from-to) | 169-171 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Issue number | 1 |
DOIs | |
Publication status | Published - 1 Jan 1983 |