Synthesis, crystal and molecular structure of the compound dichlorobis[2-(phenylazo)phenyl-C1N2′]tin(IV)

José L. Briansó, Xavier Solans, José Vicente

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The reaction of chloro[2-(phenylazo)phenyl]mercury(II) with metallic tin leads to dichlorobis[2-(phenylazo)phenyl]tin(IV) whose structure has been determined by X-ray diffraction. The tin atom is six-co-ordinated in a very distorted octahedral fashion with two cis chlorine and cis nitrogen atoms in the equatorial plane and two carbon atoms of the ortho-metallated phenyl groups considerably displaced from the trans axial position [C-Sn-C = 149.7(7)°].
Original languageEnglish
Pages (from-to)169-171
JournalJournal of the Chemical Society, Dalton Transactions
Issue number1
DOIs
Publication statusPublished - 1 Jan 1983

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